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Détail de l'auteur
Auteur Dee Bradshaw
Documents disponibles écrits par cet auteur
Affiner la rechercheThe flotation of magnetic and non-magnetic pyrrhotite from selected nickel ore deposits / Megan Becker in Minerals engineering, Vol. 23 N° 11-13 (Octobre 2010)
[article]
in Minerals engineering > Vol. 23 N° 11-13 (Octobre 2010) . - pp. 1045–1052
Titre : The flotation of magnetic and non-magnetic pyrrhotite from selected nickel ore deposits Type de document : texte imprimé Auteurs : Megan Becker, Auteur ; Johan De Villiers, Auteur ; Dee Bradshaw, Auteur Année de publication : 2011 Article en page(s) : pp. 1045–1052 Note générale : Génie Minier Langues : Anglais (eng) Mots-clés : Ore mineralogy Sulfide ores Oxidation Résumé : The non-stoichiometric sulfide mineral pyrrhotite (Fe(1−x)S), common to many nickel ore deposits, occurs in different crystallographic forms and compositions. A series of pyrrhotite samples derived from Canada, South Africa and Botswana whose mineralogy is well characterised, were selected here in order to develop the relationship between mineralogy and flotation performance. Using both oxygen uptake and microflotation tests, the behaviour of the different pyrrhotite types was compared in terms of the effect of pH and collector addition. Non-magnetic pyrrhotite was less reactive in terms of its oxygen uptake and showed the best collectorless flotation recovery. Magnetic pyrrhotite was more reactive and showed poor collectorless flotation performance that could be improved with the addition of xanthate collector, but only if it was not already passivated. These differences are interpreted to be a result of pyrrhotite mineralogy. This has implications that may aid the manipulation of pyrrhotite flotation performance in processing operations. DEWEY : 622 ISSN : 0892-6875 En ligne : http://www.sciencedirect.com/science/article/pii/S0892687510001676 [article] The flotation of magnetic and non-magnetic pyrrhotite from selected nickel ore deposits [texte imprimé] / Megan Becker, Auteur ; Johan De Villiers, Auteur ; Dee Bradshaw, Auteur . - 2011 . - pp. 1045–1052.
Génie Minier
Langues : Anglais (eng)
in Minerals engineering > Vol. 23 N° 11-13 (Octobre 2010) . - pp. 1045–1052
Mots-clés : Ore mineralogy Sulfide ores Oxidation Résumé : The non-stoichiometric sulfide mineral pyrrhotite (Fe(1−x)S), common to many nickel ore deposits, occurs in different crystallographic forms and compositions. A series of pyrrhotite samples derived from Canada, South Africa and Botswana whose mineralogy is well characterised, were selected here in order to develop the relationship between mineralogy and flotation performance. Using both oxygen uptake and microflotation tests, the behaviour of the different pyrrhotite types was compared in terms of the effect of pH and collector addition. Non-magnetic pyrrhotite was less reactive in terms of its oxygen uptake and showed the best collectorless flotation recovery. Magnetic pyrrhotite was more reactive and showed poor collectorless flotation performance that could be improved with the addition of xanthate collector, but only if it was not already passivated. These differences are interpreted to be a result of pyrrhotite mineralogy. This has implications that may aid the manipulation of pyrrhotite flotation performance in processing operations. DEWEY : 622 ISSN : 0892-6875 En ligne : http://www.sciencedirect.com/science/article/pii/S0892687510001676 The mineralogy and crystallography of pyrrhotite from selected nickel and PGE ore deposits / Megan Becker in Economic geology, Vol. 105 N° 5 (Août 2010)
[article]
in Economic geology > Vol. 105 N° 5 (Août 2010) . - pp. 1025-1037
Titre : The mineralogy and crystallography of pyrrhotite from selected nickel and PGE ore deposits Type de document : texte imprimé Auteurs : Megan Becker, Auteur ; Johan De Villiers, Auteur ; Dee Bradshaw, Auteur Année de publication : 2011 Article en page(s) : pp. 1025-1037 Note générale : Economic geology Langues : Anglais (eng) Mots-clés : Pyrrhotite Mineral chemistry Cristallography Index. décimale : 553 Géologie économique. Minérographie. Minéraux. Formation et gisements de minerais Résumé : The nonstoichiometric sulfide pyrrhotite (Fe(1−x)S) common to many ore deposits occurs in a variety of crystallographic forms and compositions and occasionally is also intergrown with stoichiometric troilite (FeS). In this study, the mineralogy of pyrrhotite derived from several different nickel and PGE ore deposits in South Africa, Botswana, and Canada was examined in detail in terms of pyrrhotite association, crystallography, and mineral chemistry. Pyrrhotite samples were subdivided into two-phase 6C Fe11S12 pyrrhotite intergrown with 2C FeS troilite, two-phase 4C Fe7S8 pyrrhotite intergrown with 5C Fe9S10 pyrrhotite, single-phase 5C Fe9S10 pyrrhotite and single-phase 4C Fe7S8 pyrrhotite. None of the pyrrhotite samples analyzed were classified as two-phase 4C pyrrhotite intergrown with pyrite due to the scarcity of pyrite in these samples. Average solid solution Ni contents of NC pyrrhotite (0.75 ± 0.10 wt % Ni) in this study were found to be greater than in 4C pyrrhotite (0.43 ± 0.10 wt % Ni), but only when the pyrrhotite occurred as two-phase 4C pyrrhotite intergrown with NC pyrrhotite. For single-phase pyrrhotite occurrences in this study, 4C pyrrhotite was more Ni rich (up to 2 wt % Ni) than NC pyrrhotite (0.75 ± 0.19 wt % Ni). The average atomic metal/S ratios obtained for 4C Fe7S8 pyrrhotite was 0.869 ± 0.013 (n = 699), for 5C Fe9S10 pyrrhotite was 0.895 ± 0.013 (n = 316) and for 6C Fe11S12 pyrrhotite was 0.918 ± 0.017 (n = 101). The histogram comparing metal/S ratios of all the pyrrhotite samples analyzed showed a continuum of metal/S ratios, although with frequency maxima corresponding to the ideal compositions of 4C, 5C, and 6C pyrrhotite. The presence of the continuum however, was interpreted to be representative of nonstoichiometry in the pyrrhotite structure. DEWEY : 553 ISSN : 0361-0128 En ligne : http://econgeol.geoscienceworld.org/content/105/5/1025.abstract [article] The mineralogy and crystallography of pyrrhotite from selected nickel and PGE ore deposits [texte imprimé] / Megan Becker, Auteur ; Johan De Villiers, Auteur ; Dee Bradshaw, Auteur . - 2011 . - pp. 1025-1037.
Economic geology
Langues : Anglais (eng)
in Economic geology > Vol. 105 N° 5 (Août 2010) . - pp. 1025-1037
Mots-clés : Pyrrhotite Mineral chemistry Cristallography Index. décimale : 553 Géologie économique. Minérographie. Minéraux. Formation et gisements de minerais Résumé : The nonstoichiometric sulfide pyrrhotite (Fe(1−x)S) common to many ore deposits occurs in a variety of crystallographic forms and compositions and occasionally is also intergrown with stoichiometric troilite (FeS). In this study, the mineralogy of pyrrhotite derived from several different nickel and PGE ore deposits in South Africa, Botswana, and Canada was examined in detail in terms of pyrrhotite association, crystallography, and mineral chemistry. Pyrrhotite samples were subdivided into two-phase 6C Fe11S12 pyrrhotite intergrown with 2C FeS troilite, two-phase 4C Fe7S8 pyrrhotite intergrown with 5C Fe9S10 pyrrhotite, single-phase 5C Fe9S10 pyrrhotite and single-phase 4C Fe7S8 pyrrhotite. None of the pyrrhotite samples analyzed were classified as two-phase 4C pyrrhotite intergrown with pyrite due to the scarcity of pyrite in these samples. Average solid solution Ni contents of NC pyrrhotite (0.75 ± 0.10 wt % Ni) in this study were found to be greater than in 4C pyrrhotite (0.43 ± 0.10 wt % Ni), but only when the pyrrhotite occurred as two-phase 4C pyrrhotite intergrown with NC pyrrhotite. For single-phase pyrrhotite occurrences in this study, 4C pyrrhotite was more Ni rich (up to 2 wt % Ni) than NC pyrrhotite (0.75 ± 0.19 wt % Ni). The average atomic metal/S ratios obtained for 4C Fe7S8 pyrrhotite was 0.869 ± 0.013 (n = 699), for 5C Fe9S10 pyrrhotite was 0.895 ± 0.013 (n = 316) and for 6C Fe11S12 pyrrhotite was 0.918 ± 0.017 (n = 101). The histogram comparing metal/S ratios of all the pyrrhotite samples analyzed showed a continuum of metal/S ratios, although with frequency maxima corresponding to the ideal compositions of 4C, 5C, and 6C pyrrhotite. The presence of the continuum however, was interpreted to be representative of nonstoichiometry in the pyrrhotite structure. DEWEY : 553 ISSN : 0361-0128 En ligne : http://econgeol.geoscienceworld.org/content/105/5/1025.abstract