| Titre : | Process parameters and kinetics for the electrochemical generation of cerium(IV) methanesulphonate from cerium(III) methanesulphonate (2008) |
| Auteurs : | Thasan Raju, Auteur ; C. Ahmed Basha, Auteur |
| Type de document : | Article : texte imprimé |
| Dans : | Industrial & engineering chemistry research (Vol. 47 n°22, Novembre 2008) |
| Article en page(s) : | p. 8947–8952 |
| Note générale : | Industrial chemistry |
| Langues : | Anglais |
| Tags : | Electrochemical Cerium(IV) Methanesulphonate from Cerium(III) |
| Résumé : | To study and optimize the process parameters such as current density, temperature, concentration of cerium(III) methanesulphonate and methanesulphonic acid, and kinetics for the electrochemical generation of cerium(IV) methanesulphonate in aqueous methane sulfonic acid medium. A 97% current efficiency and conversion was achieved at 5 A/dm2 current density in 0.8 M cerium(III) methanesulphonate with 2 M methanesulphonic acid medium at 50 °C temperature. |
| En ligne : | http://pubs.acs.org/doi/abs/10.1021/ie701727x |
