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Synthesis and gas transport properties of polyesters and a copolyester obtained from 4,4 - (9 - Fluorenylidene) bisphenol and 4,4 - (1 - Phenylethylidene) bisphenol / M. Isabel Loria - Bastarrachea in Industrial & engineering chemistry research, Vol. 49 N° 23 (Décembre 2010) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 49 N° 23 (Décembre 2010) . - pp. 12060–12066 Titre : Synthesis and gas transport properties of polyesters and a copolyester obtained from 4,4 - (9 - Fluorenylidene) bisphenol and 4,4 - (1 - Phenylethylidene) bisphenol Type de document : texte imprimé Auteurs : M. Isabel Loria - Bastarrachea, Auteur ; Manuel Aguilar-Vega, Auteur Année de publication : 2011 Article en page(s) : pp. 12060–12066 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Gas  Polyesters  Bisphenol Résumé : Two isophthalic polyesters synthesized from 4,4′-(9-fluorenylidene) bisphenol, BF, and 4,4′-(1-phenylethylidene) bisphenol, BAP, and a random copolyester made from BF and BAP containing 50 mol % of these aromatic diols were prepared by interfacial polymerization. The resulting polyesters show glass transition temperatures, Tg, above 200 °C and onset of decomposition temperatures above 440 °C. The values of these thermal properties in the copolyester BAP50/ISO fall between those of the polyesters. It was also found that the thermal stability and maximum on the α-transition of the damping factor, tan δ, of BF/ISO were higher than those of BAP/ISO which is an indication of higher rigidity in the former. Wide-angle X-ray diffraction measurements indicated that both the homopolyesters and copolyester were amorphous. The copolyester showed an amorphous pattern with maxima that fell between those of the polyesters. Pure gas permeation measurements in films cast from solution show that gas permeability coefficients increase as the fractional free volume, FFV, of the polyester increases. This is attributed to a lower packing in BF/ISO as compared to BAP/ISO which increases the free volume available for gas permeation. The copolyester shows FFV and permeability coefficients that are intermediate between those exhibited by the homopolyesters. It was also found that ideal gas separation factors for O2/N2, CO2/CH4, and CO2/N2 are higher for BF/ISO which also shows the highest permeability coefficients. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie100478v [article] Synthesis and gas transport properties of polyesters and a copolyester obtained from 4,4 - (9 - Fluorenylidene) bisphenol and 4,4 - (1 - Phenylethylidene) bisphenol [texte imprimé] / M. Isabel Loria - Bastarrachea, Auteur ; Manuel Aguilar-Vega, Auteur . - 2011 . - pp. 12060–12066. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 23 (Décembre 2010) . - pp. 12060–12066 Mots-clés : Gas  Polyesters  Bisphenol Résumé : Two isophthalic polyesters synthesized from 4,4′-(9-fluorenylidene) bisphenol, BF, and 4,4′-(1-phenylethylidene) bisphenol, BAP, and a random copolyester made from BF and BAP containing 50 mol % of these aromatic diols were prepared by interfacial polymerization. The resulting polyesters show glass transition temperatures, Tg, above 200 °C and onset of decomposition temperatures above 440 °C. The values of these thermal properties in the copolyester BAP50/ISO fall between those of the polyesters. It was also found that the thermal stability and maximum on the α-transition of the damping factor, tan δ, of BF/ISO were higher than those of BAP/ISO which is an indication of higher rigidity in the former. Wide-angle X-ray diffraction measurements indicated that both the homopolyesters and copolyester were amorphous. The copolyester showed an amorphous pattern with maxima that fell between those of the polyesters. Pure gas permeation measurements in films cast from solution show that gas permeability coefficients increase as the fractional free volume, FFV, of the polyester increases. This is attributed to a lower packing in BF/ISO as compared to BAP/ISO which increases the free volume available for gas permeation. The copolyester shows FFV and permeability coefficients that are intermediate between those exhibited by the homopolyesters. It was also found that ideal gas separation factors for O2/N2, CO2/CH4, and CO2/N2 are higher for BF/ISO which also shows the highest permeability coefficients. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie100478v