Development of poly(Ether Ether Ketone) (Peek) with inorganic filler for direct methanol fuel cells (DMFCS) / Jitrada Auimviriyavat in Industrial & engineering chemistry research, Vol. 50 N° 22 (Novembre 2011)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 50 N° 22 (Novembre 2011) . - pp. 12527-12533 Titre : Development of poly(Ether Ether Ketone) (Peek) with inorganic filler for direct methanol fuel cells (DMFCS) Type de document : texte imprimé Auteurs : Jitrada Auimviriyavat, Auteur ; Sairung Changkhamchom, Auteur ; Anuvat Sirivat, Auteur Année de publication : 2012 Article en page(s) : pp. 12527-12533 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Fuel cell Filler Résumé : Poly(ether ether ketone) (PEEK) is an organic polymer with excellent thermal stability, chemical resistance, and mechanical properties, that are retained at high temperature. In this study, PEEK was sulfonated with concentrated sulfuric acid (98%) at various degrees of sulfonation (DS) using sulfonation times between 2 and 5 h at a constant temperature of 50 °C. The properties and chemical structure of the sulfonated membranes (S-PEEK) were investigated using TGA, XRD, and FT-IR. In this study, the methanol permeability, thermal and mechanical properties, and proton conductivity of composite membranes were measured for the effect of Ferrierite zeolite as inorganic filler at various amounts (5,10,15,17, and 20% v/v). The proton conductivity and methanol permeability values of the composite membranes were measured compared to those of a commercial membrane, Nafion 117. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24745726 [article] Development of poly(Ether Ether Ketone) (Peek) with inorganic filler for direct methanol fuel cells (DMFCS) [texte imprimé] / Jitrada Auimviriyavat, Auteur ; Sairung Changkhamchom, Auteur ; Anuvat Sirivat, Auteur . - 2012 . - pp. 12527-12533. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 22 (Novembre 2011) . - pp. 12527-12533 Mots-clés : Fuel cell Filler Résumé : Poly(ether ether ketone) (PEEK) is an organic polymer with excellent thermal stability, chemical resistance, and mechanical properties, that are retained at high temperature. In this study, PEEK was sulfonated with concentrated sulfuric acid (98%) at various degrees of sulfonation (DS) using sulfonation times between 2 and 5 h at a constant temperature of 50 °C. The properties and chemical structure of the sulfonated membranes (S-PEEK) were investigated using TGA, XRD, and FT-IR. In this study, the methanol permeability, thermal and mechanical properties, and proton conductivity of composite membranes were measured for the effect of Ferrierite zeolite as inorganic filler at various amounts (5,10,15,17, and 20% v/v). The proton conductivity and methanol permeability values of the composite membranes were measured compared to those of a commercial membrane, Nafion 117. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=24745726

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