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Thermodynamic analysis of solid – liquid phase equilibria of nitrate salts / Scott M. Davison in Industrial & engineering chemistry research, Vol. 50 N° 22 (Novembre 2011) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 50 N° 22 (Novembre 2011) . - pp. 12617–12625 Titre : Thermodynamic analysis of solid – liquid phase equilibria of nitrate salts Type de document : texte imprimé Auteurs : Scott M. Davison, Auteur ; Amy C. Sun, Auteur Année de publication : 2012 Article en page(s) : pp. 12617–12625 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Thermodynamic Résumé : In this work, we analyze solid–liquid phase equilibria of molten nitrate salt mixtures. Molten salts are used as heat transfer fluids within concentrated solar power systems. Further understanding of the thermophysical properties of the salt solutions is integral to designing the newest generation of solar power systems. We make use of classical thermodynamics to quickly model the phase equilibrium of mixtures of nitrate salts. This modeling work can serve as a complement to existing experimental efforts in identifying appropriate multicomponent salt mixtures for solar power applications. We present phase calculations of ternary and quaternary mixtures of LiNO3, NaNO3, KNO3, and CsNO3 modeled using the Wilson equation for liquid phase activity coefficients and binary solid–liquid equilibrium data. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie200581g [article] Thermodynamic analysis of solid – liquid phase equilibria of nitrate salts [texte imprimé] / Scott M. Davison, Auteur ; Amy C. Sun, Auteur . - 2012 . - pp. 12617–12625. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 50 N° 22 (Novembre 2011) . - pp. 12617–12625 Mots-clés : Thermodynamic Résumé : In this work, we analyze solid–liquid phase equilibria of molten nitrate salt mixtures. Molten salts are used as heat transfer fluids within concentrated solar power systems. Further understanding of the thermophysical properties of the salt solutions is integral to designing the newest generation of solar power systems. We make use of classical thermodynamics to quickly model the phase equilibrium of mixtures of nitrate salts. This modeling work can serve as a complement to existing experimental efforts in identifying appropriate multicomponent salt mixtures for solar power applications. We present phase calculations of ternary and quaternary mixtures of LiNO3, NaNO3, KNO3, and CsNO3 modeled using the Wilson equation for liquid phase activity coefficients and binary solid–liquid equilibrium data. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie200581g