Synthesis of dimethyl carbonate from methanol and carbon dioxide / Valerie Eta in Industrial & engineering chemistry research, Vol. 49 N° 20 (Octobre 2010)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 49 N° 20 (Octobre 2010) . - pp. 9609–9617 Titre : Synthesis of dimethyl carbonate from methanol and carbon dioxide : Circumventing thermodynamic limitations Type de document : texte imprimé Auteurs : Valerie Eta, Auteur ; Paivi Maki-Arvela, Auteur ; Anne-Riikka Leino, Auteur Année de publication : 2011 Article en page(s) : pp. 9609–9617 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Carbon dioxide Résumé : The synthesis of dimethyl carbonate from methanol and CO2 catalyzed by ZrO2 doped with KCl was investigated using chemical traps for water to circumvent thermodynamic limitations. The reaction, promoted by magnesium, occurred via the formation of carbonated magnesium methoxide (CMM) which adsorbed on the surface of ZrO2. The surface migration of the oxygen atom of ZrO2 to the surface methoxy groups of CMM resulted in the formation of dimethyl carbonate. The resulting MgO then reacted with methanol forming water and regenerating magnesium methoxide. The water formed reacted with the dehydrating agent, thus shifting the equilibrium toward a higher yield of DMC. The yield of 7.2 mol % DMC and 13.6 mol % conversion of methanol was obtained when methanol reacted with CO2 at 150 °C and 9.5 MPa for 8 h. The plausible reaction pathway is described. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=23325778 [article] Synthesis of dimethyl carbonate from methanol and carbon dioxide : Circumventing thermodynamic limitations [texte imprimé] / Valerie Eta, Auteur ; Paivi Maki-Arvela, Auteur ; Anne-Riikka Leino, Auteur . - 2011 . - pp. 9609–9617. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 20 (Octobre 2010) . - pp. 9609–9617 Mots-clés : Carbon dioxide Résumé : The synthesis of dimethyl carbonate from methanol and CO2 catalyzed by ZrO2 doped with KCl was investigated using chemical traps for water to circumvent thermodynamic limitations. The reaction, promoted by magnesium, occurred via the formation of carbonated magnesium methoxide (CMM) which adsorbed on the surface of ZrO2. The surface migration of the oxygen atom of ZrO2 to the surface methoxy groups of CMM resulted in the formation of dimethyl carbonate. The resulting MgO then reacted with methanol forming water and regenerating magnesium methoxide. The water formed reacted with the dehydrating agent, thus shifting the equilibrium toward a higher yield of DMC. The yield of 7.2 mol % DMC and 13.6 mol % conversion of methanol was obtained when methanol reacted with CO2 at 150 °C and 9.5 MPa for 8 h. The plausible reaction pathway is described. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=23325778

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