Article : texte imprimé

Synthesis of dimethyl carbonate from methanol and carbon dioxide : Circumventing thermodynamic limitations

Valerie Eta, Auteur ; Paivi Maki-Arvela, Auteur ; Anne-Riikka Leino, Auteur |

Dans Industrial & engineering chemistry research (Vol. 49 N° 20, Octobre 2010)

The synthesis of dimethyl carbonate from methanol and CO2 catalyzed by ZrO2 doped with KCl was investigated using chemical traps for water to circumvent thermodynamic limitations. The reaction, promoted by magnesium, occurred via the formation o[...]

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