Hydrometallurgical process development for the production of a zinc sulphate liquor suitable for electrowinning / D. Herrero in Minerals engineering, Vol. 23 N° 6 (Mai 2010)  

Public ISBD [article]  inMinerals engineering > Vol. 23 N° 6 (Mai 2010) . - pp. 511–517 Titre : Hydrometallurgical process development for the production of a zinc sulphate liquor suitable for electrowinning Type de document : texte imprimé Auteurs : D. Herrero, Auteur ; P.L. Arias, Auteur ; B. Güemez, Auteur Année de publication : 2011 Article en page(s) : pp. 511–517 Note générale : Génie Minier Langues : Anglais (eng) Mots-clés : Electrowinning Hydrometallurgy Leaching Wasteprocessing Résumé : This study deals with the development of an innovative hydrometallurgical process for zinc recovery from Waelz Oxide, a concentrate of zinc and lead oxides obtained pyrometallurgically from the treatment of EAF dusts. Its main objective is the production of a zinc sulphate liquor to be used as feedstock in electrolytic processes. The process requires different stages to achieve this goal. The first stage consists of a double-sulphuric-acid-leaching, achieving a 88% lixiviation of the zinc present in the Waelz Oxide. After the leaching, to fulfil the strict requirements of an electrolysis feed, some purifying stages, such as oxidation, removing more than the 99% of the iron present in the leach liquor, and cementation to remove cadmium, lead and copper were investigated. Finally, if the concentration of some metallic impurity is above the accepted level for electrolytic processes, an additional purification stage could be considered. Through this process, sulphate zinc liquors with a zinc purity of around 99.75%, containing less than 135 ppm of metallic impurities, could be obtained. DEWEY : 622 ISSN : 0892-6875 En ligne : http://www.sciencedirect.com/science/article/pii/S0892687510000221 [article] Hydrometallurgical process development for the production of a zinc sulphate liquor suitable for electrowinning [texte imprimé] / D. Herrero, Auteur ; P.L. Arias, Auteur ; B. Güemez, Auteur . - 2011 . - pp. 511–517. Génie Minier Langues : Anglais (eng) in Minerals engineering > Vol. 23 N° 6 (Mai 2010) . - pp. 511–517 Mots-clés : Electrowinning Hydrometallurgy Leaching Wasteprocessing Résumé : This study deals with the development of an innovative hydrometallurgical process for zinc recovery from Waelz Oxide, a concentrate of zinc and lead oxides obtained pyrometallurgically from the treatment of EAF dusts. Its main objective is the production of a zinc sulphate liquor to be used as feedstock in electrolytic processes. The process requires different stages to achieve this goal. The first stage consists of a double-sulphuric-acid-leaching, achieving a 88% lixiviation of the zinc present in the Waelz Oxide. After the leaching, to fulfil the strict requirements of an electrolysis feed, some purifying stages, such as oxidation, removing more than the 99% of the iron present in the leach liquor, and cementation to remove cadmium, lead and copper were investigated. Finally, if the concentration of some metallic impurity is above the accepted level for electrolytic processes, an additional purification stage could be considered. Through this process, sulphate zinc liquors with a zinc purity of around 99.75%, containing less than 135 ppm of metallic impurities, could be obtained. DEWEY : 622 ISSN : 0892-6875 En ligne : http://www.sciencedirect.com/science/article/pii/S0892687510000221

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