A novel aqueous route to fabricate ultrasmall monodisperse lipophilic cerium oxide nanoparticles / Thadathil S. Sreeremya in Industrial & engineering chemistry research, Vol. 51 N° 1 (Janvier 2012)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 51 N° 1 (Janvier 2012) . - pp. 318-326 Titre : A novel aqueous route to fabricate ultrasmall monodisperse lipophilic cerium oxide nanoparticles Type de document : texte imprimé Auteurs : Thadathil S. Sreeremya, Auteur ; Kunnambeth M. Thulasi, Auteur ; Asha Krishnan, Auteur Année de publication : 2012 Article en page(s) : pp. 318-326 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Nanoparticle Résumé : Ultrasmall monodisperse 2.3 nm CeO2 nanoparticles have been synthesized by simple ammonia precipitation of cerium nitrate in a mixed glycol―water solvent and phase transferred into apolar solvents. Cerium oxide crystal surfaces were passivated with oleic acid (OA) by reflux under ambient pressure conditions. OA molecules were chemisorbed on the ceria nanoparticle surfaces. Preferential growth of the {100} planes has been observed, ascribed to restricted growth of {111} faces due to adsorbed OA The surfacted CeO2 nanoparticles were dispersed into a stable, colloidal suspension of fine particles in hydrocarbon solvents. The CeO2 nanocrystals were characterized by X-ray diffraction, Fourier transform infrared spectra, and Raman spectral methods. Transmission electron microscopic images and photon scattering studies proved that the colloidal particles in hydrocarbon solvent were indeed monocrystalline with one crystallite per particle, monodispersed with a narrow size distribution. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=25476476 [article] A novel aqueous route to fabricate ultrasmall monodisperse lipophilic cerium oxide nanoparticles [texte imprimé] / Thadathil S. Sreeremya, Auteur ; Kunnambeth M. Thulasi, Auteur ; Asha Krishnan, Auteur . - 2012 . - pp. 318-326. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 1 (Janvier 2012) . - pp. 318-326 Mots-clés : Nanoparticle Résumé : Ultrasmall monodisperse 2.3 nm CeO2 nanoparticles have been synthesized by simple ammonia precipitation of cerium nitrate in a mixed glycol―water solvent and phase transferred into apolar solvents. Cerium oxide crystal surfaces were passivated with oleic acid (OA) by reflux under ambient pressure conditions. OA molecules were chemisorbed on the ceria nanoparticle surfaces. Preferential growth of the {100} planes has been observed, ascribed to restricted growth of {111} faces due to adsorbed OA The surfacted CeO2 nanoparticles were dispersed into a stable, colloidal suspension of fine particles in hydrocarbon solvents. The CeO2 nanocrystals were characterized by X-ray diffraction, Fourier transform infrared spectra, and Raman spectral methods. Transmission electron microscopic images and photon scattering studies proved that the colloidal particles in hydrocarbon solvent were indeed monocrystalline with one crystallite per particle, monodispersed with a narrow size distribution. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=25476476

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