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Solvent selection for the desorption of acrylonitrile from dowex optipore L - 493 / Christine Wegmann in Industrial & engineering chemistry research, Vol. 51 N° 1 (Janvier 2012) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 51 N° 1 (Janvier 2012) . - pp. 474-479 Titre : Solvent selection for the desorption of acrylonitrile from dowex optipore L - 493 Type de document : texte imprimé Auteurs : Christine Wegmann, Auteur ; Tanja Dekic Zivkovic, Auteur ; Piet J. A. M. Kerkhof, Auteur Année de publication : 2012 Article en page(s) : pp. 474-479 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Desorption Résumé : Dissolved acrylonitrile can be separated from water by adsorption onto a polymeric sorbent in a fixed bed. Switching the liquid phase from water in the adsorption step to another solvent in the desorption step can enhance the desorption of acrylonitrile from the sorbent. The selection of this solvent is the aim of this study. As a first step, computer aided molecular design was used to confine the experimental search domain. In this search the functional groups acetyl, alcohol, and amine appeared as parts of the potential solvents. As a second step, five organic solvents containing these functional groups were chosen. As a last step, the selected solvents were tested by performing adsorption experiments. Acetone was finally selected as desorption solvent for the adsorption-desorption process. This study demonstrates that by combining computer aided molecular design with experimental work, a wide range of solvents can be efficiently screened in a short time. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=25476491 [article] Solvent selection for the desorption of acrylonitrile from dowex optipore L - 493 [texte imprimé] / Christine Wegmann, Auteur ; Tanja Dekic Zivkovic, Auteur ; Piet J. A. M. Kerkhof, Auteur . - 2012 . - pp. 474-479. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 1 (Janvier 2012) . - pp. 474-479 Mots-clés : Desorption Résumé : Dissolved acrylonitrile can be separated from water by adsorption onto a polymeric sorbent in a fixed bed. Switching the liquid phase from water in the adsorption step to another solvent in the desorption step can enhance the desorption of acrylonitrile from the sorbent. The selection of this solvent is the aim of this study. As a first step, computer aided molecular design was used to confine the experimental search domain. In this search the functional groups acetyl, alcohol, and amine appeared as parts of the potential solvents. As a second step, five organic solvents containing these functional groups were chosen. As a last step, the selected solvents were tested by performing adsorption experiments. Acetone was finally selected as desorption solvent for the adsorption-desorption process. This study demonstrates that by combining computer aided molecular design with experimental work, a wide range of solvents can be efficiently screened in a short time. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=25476491