Defects and minor phases in O + and Zr + Ion Co - implanted SrTiO3 / Weilin Jiang in Industrial & engineering chemistry research, Vol. 51 N° 2 (Janvier 2012)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 51 N° 2 (Janvier 2012) . - pp. 621-628 Titre : Defects and minor phases in O + and Zr + Ion Co - implanted SrTiO3 Type de document : texte imprimé Auteurs : Weilin Jiang, Auteur ; Mark E. Bowden, Auteur ; Zihua Zhu, Auteur Année de publication : 2012 Article en page(s) : pp. 621-628 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Defect Résumé : This article reports on a comprehensive experimental study of 16O+ and 90Zr+ ion co-implanted SrTiO3 (STO) single crystals. In this study, STO was used as a model material to simulate a waste form for disposal of radioactive 90Sr that decays to 90Y and subsequently to 90Zr by emission of β– particles. Sequential 16O+ and 90Zr+ ion implantation at 550 K was performed and Zr and O atomic concentrations of up to 1.5 atom % each in STO were achieved. A number of analytical methods were employed to characterize the implanted STO, including secondary-ion mass spectroscopy, multiaxial ion-channeling analysis, and high-resolution X-ray diffraction. The results show that a high defect concentration was generated and accumulated in STO during the ion implantation, but the crystal structure was not rendered fully amorphous. Thermal annealing at 1273 K leads to a significant defect recovery at the surface with little recovery occurring at the damage peak, where a modest recovery occurs upon further annealing at 1423 K. Some of the implanted Zr species are well aligned with the STO 001 axis, but nearly all are barely located at the substitutional sites due to structural distortion. A minor phase with a tetragonal structure is observed in the Zr distributed region, which has the 001 axis parallel to that of the STO host. The tetragonal phase survived annealing at 1423 K with only a small decrease in the c parameter. A general assessment of the model waste form is also provided in this report. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=25476392 [article] Defects and minor phases in O + and Zr + Ion Co - implanted SrTiO3 [texte imprimé] / Weilin Jiang, Auteur ; Mark E. Bowden, Auteur ; Zihua Zhu, Auteur . - 2012 . - pp. 621-628. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 2 (Janvier 2012) . - pp. 621-628 Mots-clés : Defect Résumé : This article reports on a comprehensive experimental study of 16O+ and 90Zr+ ion co-implanted SrTiO3 (STO) single crystals. In this study, STO was used as a model material to simulate a waste form for disposal of radioactive 90Sr that decays to 90Y and subsequently to 90Zr by emission of β– particles. Sequential 16O+ and 90Zr+ ion implantation at 550 K was performed and Zr and O atomic concentrations of up to 1.5 atom % each in STO were achieved. A number of analytical methods were employed to characterize the implanted STO, including secondary-ion mass spectroscopy, multiaxial ion-channeling analysis, and high-resolution X-ray diffraction. The results show that a high defect concentration was generated and accumulated in STO during the ion implantation, but the crystal structure was not rendered fully amorphous. Thermal annealing at 1273 K leads to a significant defect recovery at the surface with little recovery occurring at the damage peak, where a modest recovery occurs upon further annealing at 1423 K. Some of the implanted Zr species are well aligned with the STO 001 axis, but nearly all are barely located at the substitutional sites due to structural distortion. A minor phase with a tetragonal structure is observed in the Zr distributed region, which has the 001 axis parallel to that of the STO host. The tetragonal phase survived annealing at 1423 K with only a small decrease in the c parameter. A general assessment of the model waste form is also provided in this report. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=25476392

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