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Lime treatment of prehydrolysis liquor from the kraft - based dissolving pulp production process / Jing Shen in Industrial & engineering chemistry research, Vol. 51 N° 2 (Janvier 2012) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 51 N° 2 (Janvier 2012) . - pp. 662–667 Titre : Lime treatment of prehydrolysis liquor from the kraft - based dissolving pulp production process Type de document : texte imprimé Auteurs : Jing Shen, Auteur ; Pedram Fatehi, Auteur ; Pendar Soleimani, Auteur Année de publication : 2012 Article en page(s) : pp. 662–667 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Prehydrolysis  liquor Résumé : In this study, the concept of using lime for the treatment of industrially produced prehydrolysis liquor (PHL) of kraft-based dissolving pulp production process was tested, and its effect on the concentrations of acetic acid, furfural, UV lignin, and hemicelluloses was explored. Lime treatment resulted in a significant increase in the acetic acid concentration due to alkaline hydrolysis of the acetyl groups bound to the dissolved hemicelluloses in PHL, and the degradation of sugars. At relatively high lime dosages (e.g., above 1.7%), furfural was completely eliminated, while the lignin concentration decreased by 20–25%. The hemicelluloses concentration can be significantly decreased due to the alkaline oxidative degradation. However, when performed in the absence of oxygen/air by bubbling carbon dioxide to the lime/PHL system, the degradation of hemicelluloses was effectively minimized. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie2019195 [article] Lime treatment of prehydrolysis liquor from the kraft - based dissolving pulp production process [texte imprimé] / Jing Shen, Auteur ; Pedram Fatehi, Auteur ; Pendar Soleimani, Auteur . - 2012 . - pp. 662–667. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 2 (Janvier 2012) . - pp. 662–667 Mots-clés : Prehydrolysis  liquor Résumé : In this study, the concept of using lime for the treatment of industrially produced prehydrolysis liquor (PHL) of kraft-based dissolving pulp production process was tested, and its effect on the concentrations of acetic acid, furfural, UV lignin, and hemicelluloses was explored. Lime treatment resulted in a significant increase in the acetic acid concentration due to alkaline hydrolysis of the acetyl groups bound to the dissolved hemicelluloses in PHL, and the degradation of sugars. At relatively high lime dosages (e.g., above 1.7%), furfural was completely eliminated, while the lignin concentration decreased by 20–25%. The hemicelluloses concentration can be significantly decreased due to the alkaline oxidative degradation. However, when performed in the absence of oxygen/air by bubbling carbon dioxide to the lime/PHL system, the degradation of hemicelluloses was effectively minimized. DEWEY : 660 ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie2019195