Solvent free selective oxidation of styrene and benzyl alcohol to benzaldehyde over an eco - friendly and reusable catalyst, undecamolybdophosphate supported onto neutral alumina / Anjali Patel in Industrial & engineering chemistry research, Vol. 51 N° 2 (Janvier 2012)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 51 N° 2 (Janvier 2012) . - pp. 732–740 Titre : Solvent free selective oxidation of styrene and benzyl alcohol to benzaldehyde over an eco - friendly and reusable catalyst, undecamolybdophosphate supported onto neutral alumina Type de document : texte imprimé Auteurs : Anjali Patel, Auteur ; Soyeb Pathan, Auteur Année de publication : 2012 Article en page(s) : pp. 732–740 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Catalyst Oxidation Résumé : Supported undecamolybdophosphate was synthesized and characterized by various physicochemical techniques and successfully used for solvent free oxidation of styrene and of benzyl alcohol to benzaldehyde. Influence of the reaction parameters (molar ratio of substrate to H2O2, amount of the catalyst, reaction time, and reaction temperature) were studied. The catalyst was reused three times without any significant loss in the catalytic activity. FT-IR, XRD, and DRS of regenerated catalyst indicated that the catalyst was undegraded and stable after the reaction. The novelty of the work lies in obtaining a single selective product, benzaldehyde, as well as a high TON for the same, under mild conditions. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=25476406 [article] Solvent free selective oxidation of styrene and benzyl alcohol to benzaldehyde over an eco - friendly and reusable catalyst, undecamolybdophosphate supported onto neutral alumina [texte imprimé] / Anjali Patel, Auteur ; Soyeb Pathan, Auteur . - 2012 . - pp. 732–740. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 2 (Janvier 2012) . - pp. 732–740 Mots-clés : Catalyst Oxidation Résumé : Supported undecamolybdophosphate was synthesized and characterized by various physicochemical techniques and successfully used for solvent free oxidation of styrene and of benzyl alcohol to benzaldehyde. Influence of the reaction parameters (molar ratio of substrate to H2O2, amount of the catalyst, reaction time, and reaction temperature) were studied. The catalyst was reused three times without any significant loss in the catalytic activity. FT-IR, XRD, and DRS of regenerated catalyst indicated that the catalyst was undegraded and stable after the reaction. The novelty of the work lies in obtaining a single selective product, benzaldehyde, as well as a high TON for the same, under mild conditions. DEWEY : 660 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=25476406

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