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Synthesis and Isolation of Methyl Acetate through Heterogeneous Catalysis with Liquid−Liquid Extraction / Susanne Lux in Industrial & engineering chemistry research, Vol. 49 N° 21 (Novembre 2010) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 49 N° 21 (Novembre 2010) . - pp. 10274-10278 Titre : Synthesis and Isolation of Methyl Acetate through Heterogeneous Catalysis with Liquid−Liquid Extraction Type de document : texte imprimé Auteurs : Susanne Lux, Auteur ; Thomas Winkler, Auteur ; Matthaus Siebenhofer, Auteur Année de publication : 2011 Article en page(s) : pp. 10274-10278 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Liquid  liquid  extraction  Heterogeneous  catalysis Résumé : Formation of azeotropic mixtures may cause difficulties in separation. Synthesis and isolation of methyl acetate is a representative example for formation of azeotropic product mixtures. In this project chemical reaction engineering in batch and plug flow reactor, as well as the combination of synthesis with extractive isolation of methyl acetate from the multi component mixture methanol/acetic acid/methyl acetate/water, were investigated. Reaction paths were discussed in order to avoid or bypass the low boiling azeotropic mixtures of methyl acetate with water and methanol. The esterification reaction was heterogeneously catalyzed with cation exchange resins. For extractive separation of methyl acetate aliphatic hydrocarbons of the C8 to C10 class were used. The project provides the basic strategy for process design of esterification processes. In the concept of process intensification, alternative process routes in methyl acetate synthesis and isolation were discussed. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=23447917 [article] Synthesis and Isolation of Methyl Acetate through Heterogeneous Catalysis with Liquid−Liquid Extraction [texte imprimé] / Susanne Lux, Auteur ; Thomas Winkler, Auteur ; Matthaus Siebenhofer, Auteur . - 2011 . - pp. 10274-10278. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 21 (Novembre 2010) . - pp. 10274-10278 Mots-clés : Liquid  liquid  extraction  Heterogeneous  catalysis Résumé : Formation of azeotropic mixtures may cause difficulties in separation. Synthesis and isolation of methyl acetate is a representative example for formation of azeotropic product mixtures. In this project chemical reaction engineering in batch and plug flow reactor, as well as the combination of synthesis with extractive isolation of methyl acetate from the multi component mixture methanol/acetic acid/methyl acetate/water, were investigated. Reaction paths were discussed in order to avoid or bypass the low boiling azeotropic mixtures of methyl acetate with water and methanol. The esterification reaction was heterogeneously catalyzed with cation exchange resins. For extractive separation of methyl acetate aliphatic hydrocarbons of the C8 to C10 class were used. The project provides the basic strategy for process design of esterification processes. In the concept of process intensification, alternative process routes in methyl acetate synthesis and isolation were discussed. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=23447917