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Assessment of current chemiluminescence kinetics models at engine conditions / Eric Petersen in Transactions of the ASME . Journal of engineering for gas turbines and power, Vol. 134 N° 5 (Mai 2012) 

Public ISBD [article]  in Transactions of the ASME . Journal of engineering for gas turbines and power > Vol. 134 N° 5 (Mai 2012) . - 07 p. Titre : Assessment of current chemiluminescence kinetics models at engine conditions Type de document : texte imprimé Auteurs : Eric Petersen, Auteur ; Madeleine Kopp, Auteur ; Nicole Donato, Auteur ; Felix Güthe, Auteur Année de publication : 2012 Article en page(s) : 07 p. Note générale : Génie mécanique Langues : Anglais (eng) Mots-clés : Chemiluminescence  Engines  Gas  turbines  Reaction  kinetics Index. décimale : 620.1 Essais des matériaux. Défauts des matériaux. Protection des matériaux Résumé : Chemiluminescence continues to be of interest as a cost-effective optical diagnostic for gas turbine combustor health monitoring. However, most chemical kinetics mechanisms of the chemiluminescence of target species such as OH*, CH*, and CO2* were developed from atmospheric-pressure data. The present paper presents a study wherein the ability of current kinetics models to predict the chemiluminescence trends at engine pressures was assessed. Shock-tube experiments were performed in highly diluted mixtures of H2/O2/Ar at a wide range of pressures to evaluate the ability of a current kinetics model to predict the measured trends. At elevated pressures up to 15 atm, the currently used reaction rate of H + O + M = OH* + M (i.e., without any pressure dependence) significantly over predicts the amount of OH* formed. Other important chemiluminescence species include CH* and CO2*, and separate experiments were performed to assess the validity of existing chemical kinetics mechanisms for both of these species at elevated pressures. A pressure excursion using methane-oxygen mixtures highly diluted in argon was performed up to about 15 atm, and the time histories of CH* and CO2* were measured over a range of temperatures from about 1700 to 2300 K. It was found that the existing CH* mechanism captured the T and P trends rather well, but the CO2* mechanism did a poor job of capturing both the temperature and pressure behavior. With respect to the modeling of collider species, it was found that the current OH* model performs well for N2, but some improvements can be made for CO2. DEWEY : 620.1 ISSN : 0742-4795 En ligne : http://asmedl.org/getabs/servlet/GetabsServlet?prog=normal&id=JETPEZ000134000005 [...] [article] Assessment of current chemiluminescence kinetics models at engine conditions [texte imprimé] / Eric Petersen, Auteur ; Madeleine Kopp, Auteur ; Nicole Donato, Auteur ; Felix Güthe, Auteur . - 2012 . - 07 p. Génie mécanique Langues : Anglais (eng) in Transactions of the ASME . Journal of engineering for gas turbines and power > Vol. 134 N° 5 (Mai 2012) . - 07 p. Mots-clés : Chemiluminescence  Engines  Gas  turbines  Reaction  kinetics Index. décimale : 620.1 Essais des matériaux. Défauts des matériaux. Protection des matériaux Résumé : Chemiluminescence continues to be of interest as a cost-effective optical diagnostic for gas turbine combustor health monitoring. However, most chemical kinetics mechanisms of the chemiluminescence of target species such as OH*, CH*, and CO2* were developed from atmospheric-pressure data. The present paper presents a study wherein the ability of current kinetics models to predict the chemiluminescence trends at engine pressures was assessed. Shock-tube experiments were performed in highly diluted mixtures of H2/O2/Ar at a wide range of pressures to evaluate the ability of a current kinetics model to predict the measured trends. At elevated pressures up to 15 atm, the currently used reaction rate of H + O + M = OH* + M (i.e., without any pressure dependence) significantly over predicts the amount of OH* formed. Other important chemiluminescence species include CH* and CO2*, and separate experiments were performed to assess the validity of existing chemical kinetics mechanisms for both of these species at elevated pressures. A pressure excursion using methane-oxygen mixtures highly diluted in argon was performed up to about 15 atm, and the time histories of CH* and CO2* were measured over a range of temperatures from about 1700 to 2300 K. It was found that the existing CH* mechanism captured the T and P trends rather well, but the CO2* mechanism did a poor job of capturing both the temperature and pressure behavior. With respect to the modeling of collider species, it was found that the current OH* model performs well for N2, but some improvements can be made for CO2. DEWEY : 620.1 ISSN : 0742-4795 En ligne : http://asmedl.org/getabs/servlet/GetabsServlet?prog=normal&id=JETPEZ000134000005 [...]

Ignition and oxidation of 50/50 butane isomer blends / Nicole Donato in Transactions of the ASME . Journal of engineering for gas turbines and power, Vol. 132 N° 5 (Mai 2010) 

Public ISBD [article]  in Transactions of the ASME . Journal of engineering for gas turbines and power > Vol. 132 N° 5 (Mai 2010) . - 09 p. Titre : Ignition and oxidation of 50/50 butane isomer blends Type de document : texte imprimé Auteurs : Nicole Donato, Auteur ; Christopher Aul, Auteur ; Eric Petersen, Auteur Année de publication : 2011 Article en page(s) : 09 p. Note générale : Génie Mécanique Langues : Anglais (eng) Mots-clés : Combustion  Gas  turbines  Ignition Index. décimale : 620.1 Essais des matériaux. Défauts des matériaux. Protection des matériaux Résumé : One of the alkanes found within gaseous fuel blends of interest to gas turbine applications is butane. There are two structural isomers of butane, normal butane and isobutane, and the combustion characteristics of either isomer are not well known. Of particular interest to this work are mixtures of n-butane and isobutane. A shock-tube experiment was performed to produce important ignition-delay-time data for these binary butane isomer mixtures, which are not currently well studied, with emphasis on 50-50 blends of the two isomers. These data represent the most extensive shock-tube results to date for mixtures of n-butane and isobutane. Ignition within the shock tube was determined from the sharp pressure rise measured at the end wall, which is characteristic of such exothermic reactions. Both experimental and kinetics modeling results are presented for a wide range of stoichiometries (phi=0.3−2.0), temperatures (1056–1598 K), and pressures (1–21 atm). The results of this work serve as a validation for the current chemical kinetics model. Correlations in the form of Arrhenius-type expressions are presented, which agree well with both the experimental results and the kinetics modeling. The results of an ignition-delay-time sensitivity analysis are provided, and key reactions are identified. The data from this study are compared with the modeling results of 100% normal butane and 100% isobutane. The 50/50 mixture of n-butane and isobutane was shown to be more readily ignitable than 100% isobutane but reacts slower than 100% n-butane only for the richer mixtures. There was little difference in ignition time between the lean mixtures. DEWEY : 620.1 ISSN : 0742-4795 En ligne : http://asmedl.org/getabs/servlet/GetabsServlet?prog=normal&id=JETPEZ000132000005 [...] [article] Ignition and oxidation of 50/50 butane isomer blends [texte imprimé] / Nicole Donato, Auteur ; Christopher Aul, Auteur ; Eric Petersen, Auteur . - 2011 . - 09 p. Génie Mécanique Langues : Anglais (eng) in Transactions of the ASME . Journal of engineering for gas turbines and power > Vol. 132 N° 5 (Mai 2010) . - 09 p. Mots-clés : Combustion  Gas  turbines  Ignition Index. décimale : 620.1 Essais des matériaux. Défauts des matériaux. Protection des matériaux Résumé : One of the alkanes found within gaseous fuel blends of interest to gas turbine applications is butane. There are two structural isomers of butane, normal butane and isobutane, and the combustion characteristics of either isomer are not well known. Of particular interest to this work are mixtures of n-butane and isobutane. A shock-tube experiment was performed to produce important ignition-delay-time data for these binary butane isomer mixtures, which are not currently well studied, with emphasis on 50-50 blends of the two isomers. These data represent the most extensive shock-tube results to date for mixtures of n-butane and isobutane. Ignition within the shock tube was determined from the sharp pressure rise measured at the end wall, which is characteristic of such exothermic reactions. Both experimental and kinetics modeling results are presented for a wide range of stoichiometries (phi=0.3−2.0), temperatures (1056–1598 K), and pressures (1–21 atm). The results of this work serve as a validation for the current chemical kinetics model. Correlations in the form of Arrhenius-type expressions are presented, which agree well with both the experimental results and the kinetics modeling. The results of an ignition-delay-time sensitivity analysis are provided, and key reactions are identified. The data from this study are compared with the modeling results of 100% normal butane and 100% isobutane. The 50/50 mixture of n-butane and isobutane was shown to be more readily ignitable than 100% isobutane but reacts slower than 100% n-butane only for the richer mixtures. There was little difference in ignition time between the lean mixtures. DEWEY : 620.1 ISSN : 0742-4795 En ligne : http://asmedl.org/getabs/servlet/GetabsServlet?prog=normal&id=JETPEZ000132000005 [...]