Liquid — solid mass transfer and reaction in a rotor — stator spinning disc reactor / Meeuwse, Marco in Industrial & engineering chemistry research, Vol. 49 N° 21 (Novembre 2010)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 49 N° 21 (Novembre 2010) . - pp. 10751-10757 Titre : Liquid — solid mass transfer and reaction in a rotor — stator spinning disc reactor Type de document : texte imprimé Auteurs : Meeuwse, Marco, Auteur ; Sanne Lempers, Auteur ; John Van Der Schaaf, Auteur Année de publication : 2011 Article en page(s) : pp. 10751-10757 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Reactor Stator Rotor Mass transfer Résumé : The heterogeneously catalyzed oxidation of glucose is performed in a rotor-stator spinning disk reactor. One side of the rotor is coated with a Pt/C and Nafion catalytic layer, resulting in a liquid-solid interfacial area of 274 mi2 mR3. At the lowest rotational disk speed, 26 rad s―1, the reaction is liquid-solid mass transfer limited; at the highest rotational disk speed, 180 rad s―1, the intrinsic kinetics are rate determining. The experimental overall reaction rates are fitted with a resistances in series model, with the activation energy, pre-exponential factor, and volumetric liquid-solid mass transfer coefficient as parameters. The volumetric liquid―solid mass transfer coefficient, kLSαLS, increases from 0.02 to 0.22 mL3 mR―3 s―1 for a rotational disk speed of 26 to 157 rad s '. These values are high in comparison to conventional reactors, like packed beds, in spite of the low liquid-solid interfacial area used in this study. The values of the liquid—solid mass transfer coefficient kLS are 1 order of magnitude higher compared to values reported for packed beds. The Sherwood number for the liquid-solid mass transfer in the rotor―stator spinning disk reactor depends on the Reynolds number to the power 2 in the range I x 105 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=23447968 [article] Liquid — solid mass transfer and reaction in a rotor — stator spinning disc reactor [texte imprimé] / Meeuwse, Marco, Auteur ; Sanne Lempers, Auteur ; John Van Der Schaaf, Auteur . - 2011 . - pp. 10751-10757. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 21 (Novembre 2010) . - pp. 10751-10757 Mots-clés : Reactor Stator Rotor Mass transfer Résumé : The heterogeneously catalyzed oxidation of glucose is performed in a rotor-stator spinning disk reactor. One side of the rotor is coated with a Pt/C and Nafion catalytic layer, resulting in a liquid-solid interfacial area of 274 mi2 mR3. At the lowest rotational disk speed, 26 rad s―1, the reaction is liquid-solid mass transfer limited; at the highest rotational disk speed, 180 rad s―1, the intrinsic kinetics are rate determining. The experimental overall reaction rates are fitted with a resistances in series model, with the activation energy, pre-exponential factor, and volumetric liquid-solid mass transfer coefficient as parameters. The volumetric liquid―solid mass transfer coefficient, kLSαLS, increases from 0.02 to 0.22 mL3 mR―3 s―1 for a rotational disk speed of 26 to 157 rad s '. These values are high in comparison to conventional reactors, like packed beds, in spite of the low liquid-solid interfacial area used in this study. The values of the liquid—solid mass transfer coefficient kLS are 1 order of magnitude higher compared to values reported for packed beds. The Sherwood number for the liquid-solid mass transfer in the rotor―stator spinning disk reactor depends on the Reynolds number to the power 2 in the range I x 105 ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=23447968

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