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A study of the densification mechanisms during spark plasma sintering of zirconium (oxy-)carbide powders / M. Gendre in Acta materialia, Vol. 58 N° 7 (Avril 2010) 

Public ISBD [article]  in Acta materialia > Vol. 58 N° 7 (Avril 2010) . - pp. 2598–2609 Titre : A study of the densification mechanisms during spark plasma sintering of zirconium (oxy-)carbide powders Type de document : texte imprimé Auteurs : M. Gendre, Auteur ; A. Maître, Auteur ; G. Trolliard, Auteur Année de publication : 2011 Article en page(s) : pp. 2598–2609 Note générale : Métallurgie Langues : Anglais (eng) Mots-clés : Carboreduction  Densification  mechanism  Zirconium  oxycarbide  Modeling  SPS Résumé : Zirconium oxycarbide powders with controlled composition ZrC0.94O0.05 were synthesized using the carboreduction of zirconia. They were further subjected to spark plasma sintering (SPS) under several applied loads (25, 50, 100 MPa). The densification mechanism of zirconium oxycarbide powders during the SPS was studied. An analytical model derived from creep deformation studies of ceramics was successfully applied to determine the mechanisms involved during the final stage of densification. These mechanisms were elucidated by evaluating the stress exponent (n) and the apparent activation energy (Ea) from the densification rate law. It was concluded that at low macroscopic applied stress (25 MPa), an intergranular glide mechanism (n ⩽ 2) governs the densification process, while a dislocation motion mechanism (n ⩾ 3) operates at higher applied load (100 MPa). Transmission electron microscopy observations confirm theses results. The samples treated at low applied stress appear almost free of dislocations, whereas samples sintered at high applied stress present a high dislocation density, forming sub-grain boundaries. High values of apparent activation energy (e.g. 687–774 kJ mol−1) are reached irrespective of the applied load, indicating that both mechanisms mentioned above are assisted by the zirconium lattice diffusion which thus appears to be the rate-limiting step for densification. DEWEY : 669 ISSN : 1359-6454 En ligne : http://www.sciencedirect.com/science/article/pii/S1359645409009045 [article] A study of the densification mechanisms during spark plasma sintering of zirconium (oxy-)carbide powders [texte imprimé] / M. Gendre, Auteur ; A. Maître, Auteur ; G. Trolliard, Auteur . - 2011 . - pp. 2598–2609. Métallurgie Langues : Anglais (eng) in Acta materialia > Vol. 58 N° 7 (Avril 2010) . - pp. 2598–2609 Mots-clés : Carboreduction  Densification  mechanism  Zirconium  oxycarbide  Modeling  SPS Résumé : Zirconium oxycarbide powders with controlled composition ZrC0.94O0.05 were synthesized using the carboreduction of zirconia. They were further subjected to spark plasma sintering (SPS) under several applied loads (25, 50, 100 MPa). The densification mechanism of zirconium oxycarbide powders during the SPS was studied. An analytical model derived from creep deformation studies of ceramics was successfully applied to determine the mechanisms involved during the final stage of densification. These mechanisms were elucidated by evaluating the stress exponent (n) and the apparent activation energy (Ea) from the densification rate law. It was concluded that at low macroscopic applied stress (25 MPa), an intergranular glide mechanism (n ⩽ 2) governs the densification process, while a dislocation motion mechanism (n ⩾ 3) operates at higher applied load (100 MPa). Transmission electron microscopy observations confirm theses results. The samples treated at low applied stress appear almost free of dislocations, whereas samples sintered at high applied stress present a high dislocation density, forming sub-grain boundaries. High values of apparent activation energy (e.g. 687–774 kJ mol−1) are reached irrespective of the applied load, indicating that both mechanisms mentioned above are assisted by the zirconium lattice diffusion which thus appears to be the rate-limiting step for densification. DEWEY : 669 ISSN : 1359-6454 En ligne : http://www.sciencedirect.com/science/article/pii/S1359645409009045