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Preparation of a catalyst for selective hydrogenation of pyrolysis gasoline / Zhiming Zhou in Industrial & engineering chemistry research, Vol. 49 N° 21 (Novembre 2010) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 49 N° 21 (Novembre 2010) . - pp. 11112-11118 Titre : Preparation of a catalyst for selective hydrogenation of pyrolysis gasoline Type de document : texte imprimé Auteurs : Zhiming Zhou, Auteur ; Tianying Zeng, Auteur ; Zhenmin Cheng, Auteur Année de publication : 2011 Article en page(s) : pp. 11112-11118 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Pyrolysis  Hydrogenation  Catalyst  Preparation Résumé : Novel palladium catalysts supported on alumina supports with the hierarchically macro-/mesoporous structure were prepared and applied to selective hydrogenation of pyrolysis gasoline. The textural, structural, and morphological properties of the catalyst supports were studied by SEM, XRD, and N2 adsorption-desorption techniques. The results showed that the hierarchically macro-/mesoporous structures of these materials were formed by a spontaneous self-assembly mechanism, and the presence of surfactant molecules, which influenced the mesopore size distribution, had almost no effects on the macroporous channels. Calcination treatments of the prepared materials revealed their high thermal stability. By comparison with a commercial catalyst without the hierarchically porous structure, these novel catalysts exhibited much better catalytic performance, that is, higher activity and selectivity, which was ascribed mainly to their unique structures of hierarchical mesopores and macropores. Finally, the stability of the novel catalysts was tested. Both experimental observations and TGA analysis of the used catalysts indicated good stability of these catalysts. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=23448009 [article] Preparation of a catalyst for selective hydrogenation of pyrolysis gasoline [texte imprimé] / Zhiming Zhou, Auteur ; Tianying Zeng, Auteur ; Zhenmin Cheng, Auteur . - 2011 . - pp. 11112-11118. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 21 (Novembre 2010) . - pp. 11112-11118 Mots-clés : Pyrolysis  Hydrogenation  Catalyst  Preparation Résumé : Novel palladium catalysts supported on alumina supports with the hierarchically macro-/mesoporous structure were prepared and applied to selective hydrogenation of pyrolysis gasoline. The textural, structural, and morphological properties of the catalyst supports were studied by SEM, XRD, and N2 adsorption-desorption techniques. The results showed that the hierarchically macro-/mesoporous structures of these materials were formed by a spontaneous self-assembly mechanism, and the presence of surfactant molecules, which influenced the mesopore size distribution, had almost no effects on the macroporous channels. Calcination treatments of the prepared materials revealed their high thermal stability. By comparison with a commercial catalyst without the hierarchically porous structure, these novel catalysts exhibited much better catalytic performance, that is, higher activity and selectivity, which was ascribed mainly to their unique structures of hierarchical mesopores and macropores. Finally, the stability of the novel catalysts was tested. Both experimental observations and TGA analysis of the used catalysts indicated good stability of these catalysts. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=23448009