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Kinetic studies on black light photocatalytic ozonation of diclofenac and sulfamethoxazole in water / Fernando J. Beltran in Industrial & engineering chemistry research, Vol. 51 N° 12 (Mars 2012) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 51 N° 12 (Mars 2012) . - pp. 4533–4544 Titre : Kinetic studies on black light photocatalytic ozonation of diclofenac and sulfamethoxazole in water Type de document : texte imprimé Auteurs : Fernando J. Beltran, Auteur ; Almudena Aguinaco, Auteur ; Ana Rey, Auteur Année de publication : 2012 Article en page(s) : pp. 4533–4544 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Kinetic  Photocatalytic  ozonation Résumé : Black light photocatalytic ozonation of two pharmaceutical compounds, sulfamethoxazole (SMX) and diclofenac (DCF), and the resulting total organic carbon (TOC) are studied. DCF and SMX removals from some mg·L–1 to 100 μg·L–1 are achieved in approximately 7 and 15 min ozonation, respectively, regardless of the ozone process, while the resulting TOC is eliminated via hydroxyl radical reactions. For initial concentrations lower than 50 μg·L–1, competition between direct ozonation and hydroxyl radical oxidation to eliminate SMX and DCF takes place. The initial reaction period for cases of high and low concentration is simulated through fast-moderate and slow gas–liquid second order reaction kinetics, respectively. For high starting concentrations the calculated results suggest the presence of ozone fast reacting intermediates. For low starting concentration, calculated results indicate the importance of hydroxyl radical oxidation and the synergic effect of ozone and photocatalytic oxidation. Kinetic data of TOC ozonation, photocatalytic oxidation, and photocatalytic ozonation are also presented. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie202525f [article] Kinetic studies on black light photocatalytic ozonation of diclofenac and sulfamethoxazole in water [texte imprimé] / Fernando J. Beltran, Auteur ; Almudena Aguinaco, Auteur ; Ana Rey, Auteur . - 2012 . - pp. 4533–4544. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 12 (Mars 2012) . - pp. 4533–4544 Mots-clés : Kinetic  Photocatalytic  ozonation Résumé : Black light photocatalytic ozonation of two pharmaceutical compounds, sulfamethoxazole (SMX) and diclofenac (DCF), and the resulting total organic carbon (TOC) are studied. DCF and SMX removals from some mg·L–1 to 100 μg·L–1 are achieved in approximately 7 and 15 min ozonation, respectively, regardless of the ozone process, while the resulting TOC is eliminated via hydroxyl radical reactions. For initial concentrations lower than 50 μg·L–1, competition between direct ozonation and hydroxyl radical oxidation to eliminate SMX and DCF takes place. The initial reaction period for cases of high and low concentration is simulated through fast-moderate and slow gas–liquid second order reaction kinetics, respectively. For high starting concentrations the calculated results suggest the presence of ozone fast reacting intermediates. For low starting concentration, calculated results indicate the importance of hydroxyl radical oxidation and the synergic effect of ozone and photocatalytic oxidation. Kinetic data of TOC ozonation, photocatalytic oxidation, and photocatalytic ozonation are also presented. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie202525f