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Study on the performance of lambda cyhalothrin microemulsion with biodiesel as an alternative solvent / Chih-Ping Chin in Industrial & engineering chemistry research, Vol. 51 N° 12 (Mars 2012) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 51 N° 12 (Mars 2012) . - pp. 4710–4718 Titre : Study on the performance of lambda cyhalothrin microemulsion with biodiesel as an alternative solvent Type de document : texte imprimé Auteurs : Chih-Ping Chin, Auteur ; Chi-Wei Lan, Auteur ; Ho-Shing Wu, Auteur Année de publication : 2012 Article en page(s) : pp. 4710–4718 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Microemulsion  Biodiesel  Solvent Résumé : This study investigates a lambda cyhalothrin 2.5% (w/w) microemulsion formulation, with biodiesel as an alternative solvent, as a potential pesticide delivery system for oil-soluble pesticide active ingredients (AIs). This study presents a pseudoternary phase diagram of the investigated system, at room temperature by titration, and the surfactant/cosurfactant mass ratios (S/C), the oil-to-surfactant/cosurfactant mass ratios (O/SC) and the optimum formulation. This study also investigates the continuous structural inversion from water-in-oil to oil-in-water microemulsions after dilution with the water phase. The electrical conductivities of the selected system at constant S/C (5:1) and O/SC (1:1.2) ratios with biodiesel were also studied, and the percolation phenomenon was observed. The study examines the performance and stability of a formulation with biodiesel in comparison to commercial formulations. Residue and phytotoxicity tests were carried out on cabbage plants in a greenhouse. Experimental results indicate that biodiesel has good handling characteristics when it forms a microemulsion. The microemulsion formulation, with biodiesel as a solvent, had an acceptable transparent appearance, broader transparency temperature range, and better performance and stability than the commercial formulation. Using biodiesel in a pesticide formulation had no adverse effects on the AI activity and is comparatively safe for crops and plants. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie201151p [article] Study on the performance of lambda cyhalothrin microemulsion with biodiesel as an alternative solvent [texte imprimé] / Chih-Ping Chin, Auteur ; Chi-Wei Lan, Auteur ; Ho-Shing Wu, Auteur . - 2012 . - pp. 4710–4718. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 12 (Mars 2012) . - pp. 4710–4718 Mots-clés : Microemulsion  Biodiesel  Solvent Résumé : This study investigates a lambda cyhalothrin 2.5% (w/w) microemulsion formulation, with biodiesel as an alternative solvent, as a potential pesticide delivery system for oil-soluble pesticide active ingredients (AIs). This study presents a pseudoternary phase diagram of the investigated system, at room temperature by titration, and the surfactant/cosurfactant mass ratios (S/C), the oil-to-surfactant/cosurfactant mass ratios (O/SC) and the optimum formulation. This study also investigates the continuous structural inversion from water-in-oil to oil-in-water microemulsions after dilution with the water phase. The electrical conductivities of the selected system at constant S/C (5:1) and O/SC (1:1.2) ratios with biodiesel were also studied, and the percolation phenomenon was observed. The study examines the performance and stability of a formulation with biodiesel in comparison to commercial formulations. Residue and phytotoxicity tests were carried out on cabbage plants in a greenhouse. Experimental results indicate that biodiesel has good handling characteristics when it forms a microemulsion. The microemulsion formulation, with biodiesel as a solvent, had an acceptable transparent appearance, broader transparency temperature range, and better performance and stability than the commercial formulation. Using biodiesel in a pesticide formulation had no adverse effects on the AI activity and is comparatively safe for crops and plants. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie201151p