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Catalytic cracking and coking of supercritical n - dodecane in microchannel coated with HZSM - 5 zeolites / Fanxu Meng in Industrial & engineering chemistry research, Vol. 49 N° 19 (Octobre 2010) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 49 N° 19 (Octobre 2010) . - pp. 8977–8983 Titre : Catalytic cracking and coking of supercritical n - dodecane in microchannel coated with HZSM - 5 zeolites Type de document : texte imprimé Auteurs : Fanxu Meng, Auteur ; Guozhu Liu, Auteur ; Shudong Qu, Auteur Année de publication : 2010 Article en page(s) : pp. 8977–8983 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Hydrocarbon  fuels  Thermal  catalytic  cracking  Microchannel Résumé : To improve the cracking rate of supercritical hydrocarbon fuels, HZSM-5 coating was prepared over the inner surface of microchannels reactors by the washcoating method. Thermal or catalytic cracking of n-dodecane, a model compound of hydrocarbon fuels, was experimentally investigated in the stainless steel microchannel coated with HZSM-5 coatings under supercritical conditions (p > 4 MPa, T > 450 °C). It is found that cracking of n-dodecane was enhanced more than 100% by HZSM-5 coatings in 30 min reaction durations at 525 and 550 °C despite gradual deactivations of catalytic activities due to conversion coke from pyrolysis and acid-catalyzed reaction. Cokes deposited on the microchannels with and without HZSM-5 coating were characterized by scanning electron microscopy (SEM) and temperature-programmed oxidation (TPO), indicating that HZSM-5 coating effectively reduces formation of filamentous cokes and its damage on the micro channel surface by shielding surface metals when the temperature is higher than 600 °C. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie101158w [article] Catalytic cracking and coking of supercritical n - dodecane in microchannel coated with HZSM - 5 zeolites [texte imprimé] / Fanxu Meng, Auteur ; Guozhu Liu, Auteur ; Shudong Qu, Auteur . - 2010 . - pp. 8977–8983. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 19 (Octobre 2010) . - pp. 8977–8983 Mots-clés : Hydrocarbon  fuels  Thermal  catalytic  cracking  Microchannel Résumé : To improve the cracking rate of supercritical hydrocarbon fuels, HZSM-5 coating was prepared over the inner surface of microchannels reactors by the washcoating method. Thermal or catalytic cracking of n-dodecane, a model compound of hydrocarbon fuels, was experimentally investigated in the stainless steel microchannel coated with HZSM-5 coatings under supercritical conditions (p > 4 MPa, T > 450 °C). It is found that cracking of n-dodecane was enhanced more than 100% by HZSM-5 coatings in 30 min reaction durations at 525 and 550 °C despite gradual deactivations of catalytic activities due to conversion coke from pyrolysis and acid-catalyzed reaction. Cokes deposited on the microchannels with and without HZSM-5 coating were characterized by scanning electron microscopy (SEM) and temperature-programmed oxidation (TPO), indicating that HZSM-5 coating effectively reduces formation of filamentous cokes and its damage on the micro channel surface by shielding surface metals when the temperature is higher than 600 °C. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie101158w