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Deep oxidative desulfurization of fuel oils catalyzed by decatungstates in the ionic liquid of [Bmim]PF6 / Huaming Li in Industrial & engineering chemistry research, Vol. 48 N° 19 (Octobre 2009) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 48 N° 19 (Octobre 2009) . - pp. 9034–9039 Titre : Deep oxidative desulfurization of fuel oils catalyzed by decatungstates in the ionic liquid of [Bmim]PF6 Type de document : texte imprimé Auteurs : Huaming Li, Auteur ; Xue Jiang, Auteur ; Wenshuai Zhu, Auteur Année de publication : 2009 Article en page(s) : pp. 9034–9039 Note générale : Chemical engineering Langues : Anglais (eng) Mots-clés : Fuel  oils  Tetrabutylammonium  decatungstate  Tetramethylammonium  decatungstate  Benzyltriethylammonium  decatungstate  Extractive  catalytic  oxidative  desulfurization  Ionic  liquid Résumé : Three decatungstates with short carbon chains as the cations, such as tetrabutylammonium decatungstate ([(C4H9)4N]4W10O32), tetramethylammonium decatungstate ([(CH3)4N]4W10O32), and benzyltriethylammonium decatungstate ([(C2H5)3NC7H7]4W10O32), were synthesized and then used as a catalyst in the extractive catalytic oxidative desulfurization (ECODS) system in the ionic liquid (IL) of [Bmim]PF6, and hydrogen dioxide (H2O2) was used as an oxidant. During the optimized process, the sulfur level in the model oil (1000 ppm S) can be reduced to 8 ppm, which is consistent with the standards of deep desulfurization. The temperature, the reaction time, and the amount of H2O2 and catalyst, as well as the type of the cations of decatungstates, all played vital roles in desulfurization efficiency, which were studied in detail to optimize the reaction conditions. The system could be recycled five times before the sulfur removal decreased sharply. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie900754f [article] Deep oxidative desulfurization of fuel oils catalyzed by decatungstates in the ionic liquid of [Bmim]PF6 [texte imprimé] / Huaming Li, Auteur ; Xue Jiang, Auteur ; Wenshuai Zhu, Auteur . - 2009 . - pp. 9034–9039. Chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 48 N° 19 (Octobre 2009) . - pp. 9034–9039 Mots-clés : Fuel  oils  Tetrabutylammonium  decatungstate  Tetramethylammonium  decatungstate  Benzyltriethylammonium  decatungstate  Extractive  catalytic  oxidative  desulfurization  Ionic  liquid Résumé : Three decatungstates with short carbon chains as the cations, such as tetrabutylammonium decatungstate ([(C4H9)4N]4W10O32), tetramethylammonium decatungstate ([(CH3)4N]4W10O32), and benzyltriethylammonium decatungstate ([(C2H5)3NC7H7]4W10O32), were synthesized and then used as a catalyst in the extractive catalytic oxidative desulfurization (ECODS) system in the ionic liquid (IL) of [Bmim]PF6, and hydrogen dioxide (H2O2) was used as an oxidant. During the optimized process, the sulfur level in the model oil (1000 ppm S) can be reduced to 8 ppm, which is consistent with the standards of deep desulfurization. The temperature, the reaction time, and the amount of H2O2 and catalyst, as well as the type of the cations of decatungstates, all played vital roles in desulfurization efficiency, which were studied in detail to optimize the reaction conditions. The system could be recycled five times before the sulfur removal decreased sharply. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie900754f

Deep oxidative desulfurization of fuels using peroxophosphomolybdate catalysts in ionic liquids / Lining He in Industrial & engineering chemistry research, Vol. 47 N°18 (Septembre 2008) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 47 N°18 (Septembre 2008) . - p. 6890–6895 Titre : Deep oxidative desulfurization of fuels using peroxophosphomolybdate catalysts in ionic liquids Type de document : texte imprimé Auteurs : Lining He, Auteur ; Huaming Li, Auteur ; Wenshuai Zhu, Auteur Année de publication : 2008 Article en page(s) : p. 6890–6895 Note générale : Chemical engineering Langues : Anglais (eng) Mots-clés : Ionic  liquid  Catalytic  oxidation  ECODS  system  Peroxophosphomolybdates Résumé : A combination of catalytic oxidation and extraction in ionic liquid (IL) was used for the removal of benzothiophene (BT), dibenzothiophene (DBT), and 4,6-dimethyldibenzothiophene (4,6-DMDBT) from the model oil. Three peroxophosphomolybdates Q3{PO4[MoO(O2)2]4} (Q = [(C4H9)4N]+, [C14H29N(CH3)3]+ and [C16H33NC5H5]+) were synthesized and characterized. In the catalytic oxidation desulfurization (CODS) system containing the peroxophosphomolybdate with short alkyl chain ([(C4H9)4N]3{PO4[MoO(O2)2]4}) and H2O2, the process exhibited low sulfur removal (16.8%). However, with addition of 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim]BF4), the extraction and catalytic oxidative desulfurization (ECODS) system remarkably increased the removal of sulfur to 97.3% (with stoichiometric amounts of H2O2). The process was superior to the simple extraction with IL (16.3%). The results demonstrated that the ECODS system could deeply remove DBT from the model oil, and this desulfurization system could be recycled 4 times with slight decrease in activity. We also found that the catalysts with short alkyl chains exhibited higher catalytic activity than that with long alkyl chain in the ECODS system. Moreover, the reactivity of sulfur compounds decreased in the order of DBT > 4,6-DMDBT > BT. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie800857a [article] Deep oxidative desulfurization of fuels using peroxophosphomolybdate catalysts in ionic liquids [texte imprimé] / Lining He, Auteur ; Huaming Li, Auteur ; Wenshuai Zhu, Auteur . - 2008 . - p. 6890–6895. Chemical engineering Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 47 N°18 (Septembre 2008) . - p. 6890–6895 Mots-clés : Ionic  liquid  Catalytic  oxidation  ECODS  system  Peroxophosphomolybdates Résumé : A combination of catalytic oxidation and extraction in ionic liquid (IL) was used for the removal of benzothiophene (BT), dibenzothiophene (DBT), and 4,6-dimethyldibenzothiophene (4,6-DMDBT) from the model oil. Three peroxophosphomolybdates Q3{PO4[MoO(O2)2]4} (Q = [(C4H9)4N]+, [C14H29N(CH3)3]+ and [C16H33NC5H5]+) were synthesized and characterized. In the catalytic oxidation desulfurization (CODS) system containing the peroxophosphomolybdate with short alkyl chain ([(C4H9)4N]3{PO4[MoO(O2)2]4}) and H2O2, the process exhibited low sulfur removal (16.8%). However, with addition of 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim]BF4), the extraction and catalytic oxidative desulfurization (ECODS) system remarkably increased the removal of sulfur to 97.3% (with stoichiometric amounts of H2O2). The process was superior to the simple extraction with IL (16.3%). The results demonstrated that the ECODS system could deeply remove DBT from the model oil, and this desulfurization system could be recycled 4 times with slight decrease in activity. We also found that the catalysts with short alkyl chains exhibited higher catalytic activity than that with long alkyl chain in the ECODS system. Moreover, the reactivity of sulfur compounds decreased in the order of DBT > 4,6-DMDBT > BT. En ligne : http://pubs.acs.org/doi/abs/10.1021/ie800857a

Heteropolyanion - based ionic liquid for deep desulfurization of fuels in ionic liquids / Wangli Huang in Industrial & engineering chemistry research, Vol. 49 N° 19 (Octobre 2010) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 49 N° 19 (Octobre 2010) . - pp. 8998–9003 Titre : Heteropolyanion - based ionic liquid for deep desulfurization of fuels in ionic liquids Type de document : texte imprimé Auteurs : Wangli Huang, Auteur ; Wenshuai Zhu, Auteur ; Huaming Li, Auteur Année de publication : 2010 Article en page(s) : pp. 8998–9003 Note générale : Chimie industrielle Langues : Anglais (eng) Mots-clés : Heteropolyanion  Ionic  liquid  Catalyst  Desulfurization Résumé : A heteropolyanion-based ionic liquid, [(3-sulfonic acid) propylpyridine]3PW12O40·2H2O, [PSPy]3PW12O40·2H2O, abbreviated [PSPy]3PW, was synthesized and approved as an effective catalyst for desulfurization of fuels in [omim]PF6 by using aqueous H2O2 as oxidant. The catalysis was fulfilled with advantages of high activity, simplified workup, and flexible recyclability. The catalytic oxidation reactivity of sulfur-containing compounds was in the order dibenzothiophene (DBT) > 4,6-dimethyldibenzothiophene (4,6-DMDBT) > benzothiophene (BT). The effects of the amount of [PSPy]3PW, H2O2, and reaction time and temperature were investigated in detail. Under the optimal conditions, the removal of DBT achieved 99.4%. Especially, we found that the removal of 4,6-DMDBT could be up to 98.8%, and the system could be recycled at least 9 times without significant decrease in activity. The sulfur level of FCC gasoline could be reduced from 360 to 70 ppm in the extraction and catalytic oxidation system. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie100234d [article] Heteropolyanion - based ionic liquid for deep desulfurization of fuels in ionic liquids [texte imprimé] / Wangli Huang, Auteur ; Wenshuai Zhu, Auteur ; Huaming Li, Auteur . - 2010 . - pp. 8998–9003. Chimie industrielle Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 19 (Octobre 2010) . - pp. 8998–9003 Mots-clés : Heteropolyanion  Ionic  liquid  Catalyst  Desulfurization Résumé : A heteropolyanion-based ionic liquid, [(3-sulfonic acid) propylpyridine]3PW12O40·2H2O, [PSPy]3PW12O40·2H2O, abbreviated [PSPy]3PW, was synthesized and approved as an effective catalyst for desulfurization of fuels in [omim]PF6 by using aqueous H2O2 as oxidant. The catalysis was fulfilled with advantages of high activity, simplified workup, and flexible recyclability. The catalytic oxidation reactivity of sulfur-containing compounds was in the order dibenzothiophene (DBT) > 4,6-dimethyldibenzothiophene (4,6-DMDBT) > benzothiophene (BT). The effects of the amount of [PSPy]3PW, H2O2, and reaction time and temperature were investigated in detail. Under the optimal conditions, the removal of DBT achieved 99.4%. Especially, we found that the removal of 4,6-DMDBT could be up to 98.8%, and the system could be recycled at least 9 times without significant decrease in activity. The sulfur level of FCC gasoline could be reduced from 360 to 70 ppm in the extraction and catalytic oxidation system. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie100234d