Activity of calcium methoxide catalyst for synthesis of high oleic palm oil based trimethylolpropane triesters as lubricant base stock / Teck-Sin Chang in Industrial & engineering chemistry research, Vol. 51 N° 15 (Avril 2012)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 51 N° 15 (Avril 2012) . - pp. 5438-5442 Titre : Activity of calcium methoxide catalyst for synthesis of high oleic palm oil based trimethylolpropane triesters as lubricant base stock Type de document : texte imprimé Auteurs : Teck-Sin Chang, Auteur ; Hassan Masood, Auteur ; Robiah Yunus, Auteur Année de publication : 2012 Article en page(s) : pp. 5438-5442 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Lubricant Catalyst Résumé : High oleic palm oil based trimethylolpropane triesters (TMPTE) are potential biodegradable base stocks for lubricant production. Calcium methoxide was used as a catalyst for the synthesis of TMPTE through chemical transesterification of high oleic palm oil methyl esters (POME) with trimethylolpropane (TMP). The effects of the main operating variables, i.e., temperature, pressure, molar ratio of TMP to POME, and the catalyst amount, on the yield of TMPTE were appraised. The amount of soap produced under these conditions was examined. The optimum conditions for the reaction were the reaction temperature set at 170 °C, molar ratio of TMP:POME set at 1:6, pressure of the system maintained at 50 mbar, and mass ratio of calcium methoxide set at 0.3% per weight of reaction mixture. Trimethylolpropane esters containing 98% w/w triesters were successfully synthesized under these conditions within 8 h reaction time. Saponification occurred under these conditions; however, the soap formation was less than that produced when homogeneous catalyst was used. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=25815821 [article] Activity of calcium methoxide catalyst for synthesis of high oleic palm oil based trimethylolpropane triesters as lubricant base stock [texte imprimé] / Teck-Sin Chang, Auteur ; Hassan Masood, Auteur ; Robiah Yunus, Auteur . - 2012 . - pp. 5438-5442. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 15 (Avril 2012) . - pp. 5438-5442 Mots-clés : Lubricant Catalyst Résumé : High oleic palm oil based trimethylolpropane triesters (TMPTE) are potential biodegradable base stocks for lubricant production. Calcium methoxide was used as a catalyst for the synthesis of TMPTE through chemical transesterification of high oleic palm oil methyl esters (POME) with trimethylolpropane (TMP). The effects of the main operating variables, i.e., temperature, pressure, molar ratio of TMP to POME, and the catalyst amount, on the yield of TMPTE were appraised. The amount of soap produced under these conditions was examined. The optimum conditions for the reaction were the reaction temperature set at 170 °C, molar ratio of TMP:POME set at 1:6, pressure of the system maintained at 50 mbar, and mass ratio of calcium methoxide set at 0.3% per weight of reaction mixture. Trimethylolpropane esters containing 98% w/w triesters were successfully synthesized under these conditions within 8 h reaction time. Saponification occurred under these conditions; however, the soap formation was less than that produced when homogeneous catalyst was used. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=25815821

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