[article]
Titre : |
Recoverable platinum nanocatalysts immobilized on magnetic spherical polyelectrolyte brushes |
Type de document : |
texte imprimé |
Auteurs : |
Shuang Wu, Auteur ; Julian Kaiser, Auteur ; Xuhong Guo, Auteur |
Année de publication : |
2012 |
Article en page(s) : |
pp. 5608-5614 |
Note générale : |
Industrial chemistry |
Langues : |
Anglais (eng) |
Mots-clés : |
Polyelectrolyte |
Résumé : |
Recoverable platinum nanocatalysts immobilized on magnetic spherical polyelectrolyte brushes (MSPB) were synthesized and characterized by high resolution transmission electron microscope (HRTEM), thermal gravimetric analysis (TGA), X-ray diffraction (XRD), and vibrating sample magnetometer (VSM). High catalytic activity was found by photometrically monitoring the reduction of 4-nitrophenol by NaBH4 in the presence of MSPB-Pt composites. An excellent stability and recyclability of catalyst was observed after consecutive eight runs following by external magnetic-separation and redispersion. This novel approach provides an excited potential application in preparation of recyclable metal nanocatalysts with high activity. |
ISSN : |
0888-5885 |
En ligne : |
http://cat.inist.fr/?aModele=afficheN&cpsidt=25815841 |
in Industrial & engineering chemistry research > Vol. 51 N° 15 (Avril 2012) . - pp. 5608-5614
[article] Recoverable platinum nanocatalysts immobilized on magnetic spherical polyelectrolyte brushes [texte imprimé] / Shuang Wu, Auteur ; Julian Kaiser, Auteur ; Xuhong Guo, Auteur . - 2012 . - pp. 5608-5614. Industrial chemistry Langues : Anglais ( eng) in Industrial & engineering chemistry research > Vol. 51 N° 15 (Avril 2012) . - pp. 5608-5614
Mots-clés : |
Polyelectrolyte |
Résumé : |
Recoverable platinum nanocatalysts immobilized on magnetic spherical polyelectrolyte brushes (MSPB) were synthesized and characterized by high resolution transmission electron microscope (HRTEM), thermal gravimetric analysis (TGA), X-ray diffraction (XRD), and vibrating sample magnetometer (VSM). High catalytic activity was found by photometrically monitoring the reduction of 4-nitrophenol by NaBH4 in the presence of MSPB-Pt composites. An excellent stability and recyclability of catalyst was observed after consecutive eight runs following by external magnetic-separation and redispersion. This novel approach provides an excited potential application in preparation of recyclable metal nanocatalysts with high activity. |
ISSN : |
0888-5885 |
En ligne : |
http://cat.inist.fr/?aModele=afficheN&cpsidt=25815841 |
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