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Kinetics of the oxidation of tetracycline hydrate by copper(II) complexed with bipyridyl in alkaline medium using chloro - complex of palladium (II) as homogeneous catalyst

Ashok Kumar Singh, Auteur ; Manjula Singh, Auteur ; Shahla Rahmani, Auteur |

Dans Industrial & engineering chemistry research (Vol. 51 N° 16, Avril 2012)

The present paper deals with the kinetics and mechanism of Pd(II)-catalyzed oxidation of tetracycline hydrate by Cu(Bip)22+ in alkaline medium. First-order kinetics with respect to [tetracycline hydrate] and fractional positive order kinetics in[...]

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