N,N - dichlorovaleramide / Pranav K. Gutch in Industrial & engineering chemistry research, Vol. 51 N° 16 (Avril 2012)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 51 N° 16 (Avril 2012) . - pp. 5830-5837 Titre : N,N - dichlorovaleramide : An efficient decontaminating reagent for sulfur mustard Type de document : texte imprimé Auteurs : Pranav K. Gutch, Auteur ; Avik Mazumder, Auteur Année de publication : 2012 Article en page(s) : pp. 5830-5837 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Chemical decontamination Gas Résumé : An efficient and operationally simple method for the chemical decontamination of sulfur mustard (HD) has been reported herein. A newly synthesized (positive chlorine bearing) reagent N,N-dichlorovaleramide has been utilized for this purpose. Decontamination has been achieved in aqueous and aprotic media. The reaction was monitored by gas chromatography-mass spectrometry and NMR spectroscopy. This reagent is more effective, stable, economical, and easy to synthesize and leads to instant decontamination of HD. The reaction was found to instantaneously and completely convert HD to innocuous products at different temperatures (-10 to 25 °C). ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie201811v [article] N,N - dichlorovaleramide : An efficient decontaminating reagent for sulfur mustard [texte imprimé] / Pranav K. Gutch, Auteur ; Avik Mazumder, Auteur . - 2012 . - pp. 5830-5837. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 16 (Avril 2012) . - pp. 5830-5837 Mots-clés : Chemical decontamination Gas Résumé : An efficient and operationally simple method for the chemical decontamination of sulfur mustard (HD) has been reported herein. A newly synthesized (positive chlorine bearing) reagent N,N-dichlorovaleramide has been utilized for this purpose. Decontamination has been achieved in aqueous and aprotic media. The reaction was monitored by gas chromatography-mass spectrometry and NMR spectroscopy. This reagent is more effective, stable, economical, and easy to synthesize and leads to instant decontamination of HD. The reaction was found to instantaneously and completely convert HD to innocuous products at different temperatures (-10 to 25 °C). ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie201811v

Exemplaires

Code-barres	Cote	Support	Localisation	Section	Disponibilité
aucun exemplaire