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Reaction kinetics and mechanism of copper(II) catalyzed oxidative deamination and decarboxylation of ornithine by peroxomonosulfate

Paramasivam Suresh Kumar, Auteur ; Radhakrishnan Mohan Raj, Auteur ; Srinivasalu Kutti Rani, Auteur |

Dans Industrial & engineering chemistry research (Vol. 51 N° 18, Mai 2012)

Copper(II) catalyzed and uncatalyzed oxidation of ornithine by peroxomonosulfate (PMS) was studied in acetic acid–sodium acetate buffered medium (pH 3.6–5.2). The catalyzed reaction was 2.6 times faster than the uncatalyzed reaction. The catalyt[...]

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