[article]
Titre : |
Cyclic imide dioximes : Formation and hydrolytic stability |
Type de document : |
texte imprimé |
Auteurs : |
Sung Ok Kang, Auteur ; Sinisa Vukovic, Auteur ; Radu Custelcean, Auteur |
Année de publication : |
2012 |
Article en page(s) : |
pp. 6619-6624 |
Note générale : |
Industrial chemistry |
Langues : |
Anglais (eng) |
Mots-clés : |
Stability |
Résumé : |
Poly(acrylamidoximes) play an important role in the uranium extraction from seawater. The present work reports solution studies of simple analogues to address the formation and stability of two binding sites present in these polymers, open-chain amidoximes and cyclic imide dioximes, including: (1) conditions that maximize the formation of the cyclic form, (2) the existence of a base-induced conversion from open-chain to cyclic form, and (3) degadation under acid and base conditions. |
ISSN : |
0888-5885 |
En ligne : |
http://cat.inist.fr/?aModele=afficheN&cpsidt=25900214 |
in Industrial & engineering chemistry research > Vol. 51 N° 19 (Mai 2012) . - pp. 6619-6624
[article] Cyclic imide dioximes : Formation and hydrolytic stability [texte imprimé] / Sung Ok Kang, Auteur ; Sinisa Vukovic, Auteur ; Radu Custelcean, Auteur . - 2012 . - pp. 6619-6624. Industrial chemistry Langues : Anglais ( eng) in Industrial & engineering chemistry research > Vol. 51 N° 19 (Mai 2012) . - pp. 6619-6624
Mots-clés : |
Stability |
Résumé : |
Poly(acrylamidoximes) play an important role in the uranium extraction from seawater. The present work reports solution studies of simple analogues to address the formation and stability of two binding sites present in these polymers, open-chain amidoximes and cyclic imide dioximes, including: (1) conditions that maximize the formation of the cyclic form, (2) the existence of a base-induced conversion from open-chain to cyclic form, and (3) degadation under acid and base conditions. |
ISSN : |
0888-5885 |
En ligne : |
http://cat.inist.fr/?aModele=afficheN&cpsidt=25900214 |
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