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Antimony(III) adsorption from aqueous solution using raw perlite and Mn - modified perlite / Ahmet Sari in Industrial & engineering chemistry research, Vol. 51 N° 19 (Mai 2012) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 51 N° 19 (Mai 2012) . - pp. 6877–6886 Titre : Antimony(III) adsorption from aqueous solution using raw perlite and Mn - modified perlite : Equilibrium, thermodynamic, and kinetic studies Type de document : texte imprimé Auteurs : Ahmet Sari, Auteur ; Gungor Sahinoglu, Auteur ; Mustafa Tuzen, Auteur Année de publication : 2012 Article en page(s) : pp. 6877–6886 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Adsorption  Aqueous  Solution  Thermodynamic  Kinetic Résumé : In this study, the adsorption potential of expanded perlite (EP) and manganese oxides-modified EP (Mn-MEP) for the removal of Sb(III) from aqueous solution were investigated. The influence of solution pH, adsorbent concentration, contact time and temperature on the Sb(III) adsorption were studied using the batch method. Modification of the surface of EP with 0.18 g of manganese oxide per gram EP showed an increase of 1.6-fold in its surface area. The raw EP and Mn-MEP samples with Sb(III) ions were characterized before and after the adsorption process using FT-IR and SEM analysis techniques. The monolayer adsorption capacity of EP and Mn-MEP for Sb(III) was found to be 54.4 and 76.5 mg g–1 at pH 4, respectively. The mean adsorption energy (6.3 kJ mol–1) calculated from the Dubinin–Radushkevich model indicated that the adsorption of Sb(III) onto Mn-MEP was physically carried out. After 10 times of adsorption/desorption cycles, the reusability of Mn-MEP decreased as slightly as 5% for adsorption and 7% for desorption. The calculated thermodynamic parameters (ΔGo, ΔHo, and ΔSo) showed that the adsorption was feasible, spontaneous, and exothermic. The kinetic parameters revealed that the adsorption of Sb(III) onto Mn-MEP followed well the pseudo-second-order kinetic model. In addition, from a practical viewpoint, Mn-MEP is a promising adsorbent for the removal of Sb(III) from aqueous solutions since it has large surface area, high adsorption capacity, easy availability, low-cost, and good reusability performance. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie300243n [article] Antimony(III) adsorption from aqueous solution using raw perlite and Mn - modified perlite : Equilibrium, thermodynamic, and kinetic studies [texte imprimé] / Ahmet Sari, Auteur ; Gungor Sahinoglu, Auteur ; Mustafa Tuzen, Auteur . - 2012 . - pp. 6877–6886. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 19 (Mai 2012) . - pp. 6877–6886 Mots-clés : Adsorption  Aqueous  Solution  Thermodynamic  Kinetic Résumé : In this study, the adsorption potential of expanded perlite (EP) and manganese oxides-modified EP (Mn-MEP) for the removal of Sb(III) from aqueous solution were investigated. The influence of solution pH, adsorbent concentration, contact time and temperature on the Sb(III) adsorption were studied using the batch method. Modification of the surface of EP with 0.18 g of manganese oxide per gram EP showed an increase of 1.6-fold in its surface area. The raw EP and Mn-MEP samples with Sb(III) ions were characterized before and after the adsorption process using FT-IR and SEM analysis techniques. The monolayer adsorption capacity of EP and Mn-MEP for Sb(III) was found to be 54.4 and 76.5 mg g–1 at pH 4, respectively. The mean adsorption energy (6.3 kJ mol–1) calculated from the Dubinin–Radushkevich model indicated that the adsorption of Sb(III) onto Mn-MEP was physically carried out. After 10 times of adsorption/desorption cycles, the reusability of Mn-MEP decreased as slightly as 5% for adsorption and 7% for desorption. The calculated thermodynamic parameters (ΔGo, ΔHo, and ΔSo) showed that the adsorption was feasible, spontaneous, and exothermic. The kinetic parameters revealed that the adsorption of Sb(III) onto Mn-MEP followed well the pseudo-second-order kinetic model. In addition, from a practical viewpoint, Mn-MEP is a promising adsorbent for the removal of Sb(III) from aqueous solutions since it has large surface area, high adsorption capacity, easy availability, low-cost, and good reusability performance. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie300243n