Reactive thermal hazards of tributyl phosphate with nitric acid / Velayuthan Sreekantan Smitha in Industrial & engineering chemistry research, Vol. 51 N° 21 (Mai 2012)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 51 N° 21 (Mai 2012) . - pp. 7205-7210 Titre : Reactive thermal hazards of tributyl phosphate with nitric acid Type de document : texte imprimé Auteurs : Velayuthan Sreekantan Smitha, Auteur ; Mahadevan Surianarayanan, Auteur ; Hariharan Seshadri, Auteur Année de publication : 2012 Article en page(s) : pp. 7205-7210 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Hazard Résumé : The accelerating rate calorimetry studies on the tributyl phosphate and nitric acid reactions at various acid concentrations revealed that the conditions for red oil formation may vary with acid strength. The accelerating rate calorimeter studies supplemented with FT-IR characterization of the end products confirmed the formation of red oil at temperatures as low as 75 °C. This study thus strongly advocates for a revisit of safety limits set in the fuel reprocessing plants to prevent red oil formation. The chemical pathway for red oil formation is worked out. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=25948461 [article] Reactive thermal hazards of tributyl phosphate with nitric acid [texte imprimé] / Velayuthan Sreekantan Smitha, Auteur ; Mahadevan Surianarayanan, Auteur ; Hariharan Seshadri, Auteur . - 2012 . - pp. 7205-7210. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 21 (Mai 2012) . - pp. 7205-7210 Mots-clés : Hazard Résumé : The accelerating rate calorimetry studies on the tributyl phosphate and nitric acid reactions at various acid concentrations revealed that the conditions for red oil formation may vary with acid strength. The accelerating rate calorimeter studies supplemented with FT-IR characterization of the end products confirmed the formation of red oil at temperatures as low as 75 °C. This study thus strongly advocates for a revisit of safety limits set in the fuel reprocessing plants to prevent red oil formation. The chemical pathway for red oil formation is worked out. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=25948461

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