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Dicumyl peroxide thermal decomposition in cumene / Ilaria Di Somma in Industrial & engineering chemistry research, Vol. 51 N° 22 (Juin 2012) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 51 N° 22 (Juin 2012) . - pp. 7493-7499 Titre : Dicumyl peroxide thermal decomposition in cumene : Development of a kinetic model Type de document : texte imprimé Auteurs : Ilaria Di Somma, Auteur ; Raffaele Marotta, Auteur ; Roberto Andreozzi, Auteur Année de publication : 2012 Article en page(s) : pp. 7493-7499 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Modeling  Kinetic  model  Thermal  decomposition Résumé : A kinetic model is developed to simulate the thermal decomposition of dicumyl peroxide (DCP) in cumene with and without oxygen in the reacting system, based on a reaction network that is comprised of a set of 51 reactions. An optimization procedure is adopted to obtain the best estimates for most of the related kinetic parameters, few of which are available in the literature. The model is successfully validated by simulating the concentration profiles of all the species participating in the decomposition of DCP in cumene, under varying initial conditions, using previously best-estimated values of the kinetic parameters. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=25968301 [article] Dicumyl peroxide thermal decomposition in cumene : Development of a kinetic model [texte imprimé] / Ilaria Di Somma, Auteur ; Raffaele Marotta, Auteur ; Roberto Andreozzi, Auteur . - 2012 . - pp. 7493-7499. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 22 (Juin 2012) . - pp. 7493-7499 Mots-clés : Modeling  Kinetic  model  Thermal  decomposition Résumé : A kinetic model is developed to simulate the thermal decomposition of dicumyl peroxide (DCP) in cumene with and without oxygen in the reacting system, based on a reaction network that is comprised of a set of 51 reactions. An optimization procedure is adopted to obtain the best estimates for most of the related kinetic parameters, few of which are available in the literature. The model is successfully validated by simulating the concentration profiles of all the species participating in the decomposition of DCP in cumene, under varying initial conditions, using previously best-estimated values of the kinetic parameters. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=25968301