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Catalytic partial oxidation of isooctane to hydrogen on rhodium catalysts / Torsten Kaltschmitt in Industrial & engineering chemistry research, Vol. 51 N° 22 (Juin 2012) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 51 N° 22 (Juin 2012) . - pp. 7536-7546 Titre : Catalytic partial oxidation of isooctane to hydrogen on rhodium catalysts : Effect of tail - gas recycling Type de document : texte imprimé Auteurs : Torsten Kaltschmitt, Auteur ; Claudia Diehm, Auteur ; Olaf Deutschmann, Auteur Année de publication : 2012 Article en page(s) : pp. 7536-7546 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Recycling  Catalyst  Isooctane  Partial  oxidation  Catalytic  reaction Résumé : Catalytic partial oxidation (CPOX) is a promising technology for reforming of liquid hydrocarbon fuels to hydrogen or synthesis gas for use in fuel cells. The addition of a certain amount of the tail gas of the fuel cell stack to the reformer inlet feed can increase overall efficiency and lead to higher H2 and CO selectivities and reduce coke formation. The effect of carbon dioxide or steam addition (1, 5, 10, 20, and 30 vol% of the total flow) on the performance of a CPOX reformer operated with isooctane as fuel surrogate is systematically studied over a wide range of C/O feed ratios (0.72―1.79) using a Rh/alumina honeycomb catalyst. The specific impact of the coreactants H2O and CO2 on reformer behavior can be interpreted by the water gas shift (WGS) chemistry. Production of H2 and CO2 increases with H2O addition at the expense of CO and H2O. Opposite trends are observed in case of CO2 addition. Tail gas recycling reduces formation of soot precursors up to 50% compared to the corresponding fuel feed without coreactants. However, tail-gas recycling shifts the formation of soot precursors toward lower C/O ratios. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=25968306 [article] Catalytic partial oxidation of isooctane to hydrogen on rhodium catalysts : Effect of tail - gas recycling [texte imprimé] / Torsten Kaltschmitt, Auteur ; Claudia Diehm, Auteur ; Olaf Deutschmann, Auteur . - 2012 . - pp. 7536-7546. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 22 (Juin 2012) . - pp. 7536-7546 Mots-clés : Recycling  Catalyst  Isooctane  Partial  oxidation  Catalytic  reaction Résumé : Catalytic partial oxidation (CPOX) is a promising technology for reforming of liquid hydrocarbon fuels to hydrogen or synthesis gas for use in fuel cells. The addition of a certain amount of the tail gas of the fuel cell stack to the reformer inlet feed can increase overall efficiency and lead to higher H2 and CO selectivities and reduce coke formation. The effect of carbon dioxide or steam addition (1, 5, 10, 20, and 30 vol% of the total flow) on the performance of a CPOX reformer operated with isooctane as fuel surrogate is systematically studied over a wide range of C/O feed ratios (0.72―1.79) using a Rh/alumina honeycomb catalyst. The specific impact of the coreactants H2O and CO2 on reformer behavior can be interpreted by the water gas shift (WGS) chemistry. Production of H2 and CO2 increases with H2O addition at the expense of CO and H2O. Opposite trends are observed in case of CO2 addition. Tail gas recycling reduces formation of soot precursors up to 50% compared to the corresponding fuel feed without coreactants. However, tail-gas recycling shifts the formation of soot precursors toward lower C/O ratios. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=25968306