Documents disponibles écrits par cet auteur

Synthesis and properties of organic – inorganic hybrid materials based on glycerol / Ignacio E. dell’Erba in Industrial & engineering chemistry research, Vol. 51 N° 22 (Juin 2012) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 51 N° 22 (Juin 2012) . - pp. 7793–7799 Titre : Synthesis and properties of organic – inorganic hybrid materials based on glycerol Type de document : texte imprimé Auteurs : Ignacio E. dell’Erba, Auteur ; Cristina E. Hoppe, Auteur ; Roberto J. J. Williams, Auteur Année de publication : 2012 Article en page(s) : pp. 7793–7799 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Organic–inorganic  hybrid  materials Résumé : The great supply of glycerol as a byproduct of the production of biodiesel has motivated interest in its use in new applications. In this study, we report the synthesis and properties of organic–inorganic hybrid materials based on glycerol. Glycerol (Gly) was reacted with 3-isocyanatopropyltriethoxysilane (IPTES) in the presence of dibutyltin dilaurate (DBTDL) as a catalyst, using a molar ratio (r = IPTES/Gly) between 0.75 and 3. The sol–gel polycondensation of the resulting precursors in the presence of a formic acid solution led to transparent solid materials with a biphasic structure consisting of glycerol-rich domains dispersed in the organic–inorganic hybrid matrix. An increase in the r value changed the hybrid materials from hydrophilic to hydrophobic. The contact angle of water droplets varied from 43.6° for r = 0.75 to 95.1° for r = 3. Each of the materials exhibited a broad glass-to-rubber transition, with the maximum of the damping peak located in the 54–70 °C range. The relatively intense tan δ peaks of the hybrid materials suggest their possible use in devices requiring vibrational damping. The maximum damping capacity corresponded to the hybrid with r = 1.5, which exhibited a loss area LA (area under the loss modulus peak) of 13.5 GPa·K. High values of the rubbery modulus were observed, varying from 130 MPa for r = 0.75 to 720 MPa for r = 3. Values of the glassy modulus were also high, and the maximum value was observed for the hybrid with r = 1.5. The hybrid materials could also be colored through the incorporation of a very small amount of functionalized gold nanoparticles. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie300393n [article] Synthesis and properties of organic – inorganic hybrid materials based on glycerol [texte imprimé] / Ignacio E. dell’Erba, Auteur ; Cristina E. Hoppe, Auteur ; Roberto J. J. Williams, Auteur . - 2012 . - pp. 7793–7799. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 22 (Juin 2012) . - pp. 7793–7799 Mots-clés : Organic–inorganic  hybrid  materials Résumé : The great supply of glycerol as a byproduct of the production of biodiesel has motivated interest in its use in new applications. In this study, we report the synthesis and properties of organic–inorganic hybrid materials based on glycerol. Glycerol (Gly) was reacted with 3-isocyanatopropyltriethoxysilane (IPTES) in the presence of dibutyltin dilaurate (DBTDL) as a catalyst, using a molar ratio (r = IPTES/Gly) between 0.75 and 3. The sol–gel polycondensation of the resulting precursors in the presence of a formic acid solution led to transparent solid materials with a biphasic structure consisting of glycerol-rich domains dispersed in the organic–inorganic hybrid matrix. An increase in the r value changed the hybrid materials from hydrophilic to hydrophobic. The contact angle of water droplets varied from 43.6° for r = 0.75 to 95.1° for r = 3. Each of the materials exhibited a broad glass-to-rubber transition, with the maximum of the damping peak located in the 54–70 °C range. The relatively intense tan δ peaks of the hybrid materials suggest their possible use in devices requiring vibrational damping. The maximum damping capacity corresponded to the hybrid with r = 1.5, which exhibited a loss area LA (area under the loss modulus peak) of 13.5 GPa·K. High values of the rubbery modulus were observed, varying from 130 MPa for r = 0.75 to 720 MPa for r = 3. Values of the glassy modulus were also high, and the maximum value was observed for the hybrid with r = 1.5. The hybrid materials could also be colored through the incorporation of a very small amount of functionalized gold nanoparticles. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie300393n