Preparation, characterization, and flame retardancy of novel rosin - based siloxane epoxy resins / Lianli Deng in Industrial & engineering chemistry research, Vol. 51 N° 24 (Juin 2012)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 51 N° 24 (Juin 2012) . - pp. 8178-8184 Titre : Preparation, characterization, and flame retardancy of novel rosin - based siloxane epoxy resins Type de document : texte imprimé Auteurs : Lianli Deng, Auteur ; Minmin Shen, Auteur ; Jing Yu, Auteur Année de publication : 2012 Article en page(s) : pp. 8178-8184 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Flame Preparation Résumé : A series of novel rosin-based siloxane epoxy resins (AESE copolymers) were prepared by the reaction of ethylene glycol diglycidyl ether modified acrylpimaric acid (AP-EGDE) with poly(methylphenylsiloxane). The chemical structures of the produced epoxy resins were determined by FTIR, 1H-NMR, 13C-NMR, and epoxy equivalent weight (EEW) test. After modification, the tensile strengths of AESE (20-40) are slightly lower than that of AP-EGDE; however their breaking elongations are higher than that of AP-EGDE remarkably. TGA results reveal that the thermal stability of AESE serials is better than that of AP-EGDE due to the formation of a protective residue. The char residue of AESE increases at 700 °C with its silicon content increases. Nevertheless, there is a peak LOI value for AESE when its silicon content is 30%. Moreover, the chemical structures of char at the end of the LOI test were analyzed by FTIR The results confirmed the formation of the protective residue. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=26029653 [article] Preparation, characterization, and flame retardancy of novel rosin - based siloxane epoxy resins [texte imprimé] / Lianli Deng, Auteur ; Minmin Shen, Auteur ; Jing Yu, Auteur . - 2012 . - pp. 8178-8184. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 24 (Juin 2012) . - pp. 8178-8184 Mots-clés : Flame Preparation Résumé : A series of novel rosin-based siloxane epoxy resins (AESE copolymers) were prepared by the reaction of ethylene glycol diglycidyl ether modified acrylpimaric acid (AP-EGDE) with poly(methylphenylsiloxane). The chemical structures of the produced epoxy resins were determined by FTIR, 1H-NMR, 13C-NMR, and epoxy equivalent weight (EEW) test. After modification, the tensile strengths of AESE (20-40) are slightly lower than that of AP-EGDE; however their breaking elongations are higher than that of AP-EGDE remarkably. TGA results reveal that the thermal stability of AESE serials is better than that of AP-EGDE due to the formation of a protective residue. The char residue of AESE increases at 700 °C with its silicon content increases. Nevertheless, there is a peak LOI value for AESE when its silicon content is 30%. Moreover, the chemical structures of char at the end of the LOI test were analyzed by FTIR The results confirmed the formation of the protective residue. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=26029653

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