Studies on mechanical poperties, thermal degradation, and combustion behaviors of poly(1,4 - butylene terephthalate)/glass fiber/cerium hypophosphite composites / Wei Yang in Industrial & engineering chemistry research, Vol. 51 N° 24 (Juin 2012)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 51 N° 24 (Juin 2012) . - pp. 8253-8261 Titre : Studies on mechanical poperties, thermal degradation, and combustion behaviors of poly(1,4 - butylene terephthalate)/glass fiber/cerium hypophosphite composites Type de document : texte imprimé Auteurs : Wei Yang, Auteur ; Ningning Hong, Auteur ; Lei Song, Auteur Année de publication : 2012 Article en page(s) : pp. 8253-8261 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Composite material Glass fiber Combustion Thermal degradation Mechanical properties Résumé : This work aims to develop glass-fiber reinforced poly(1,4-butylene terephthalate) (GRPBT) composites with enhanced mechanical, thermal stability, and flame retardancy properties using a novel compound, cerium hypophosphite (CHP). Mechanical performance studies showed that both the storage modulus and the tensile strength increased first and then decreased with increasing CHP content. For the GRPBT composite with 15 wt % of CHP, the storage modulus value at 30 °C was 3 times that of GRPBT. Thermogravimetric analysis (TGA) illustrated that low loading of CHP could improve the thermal stability of GRPBT composites. The volatilized esters measured by TGA coupled with FTIR (TGA-FTIR) in the decomposition of GRPBT with 20 wt % of CHP are decreased by about 69%. The combustion properties were evaluated by limiting oxygen index (LOI), Underwriters Laboratories 94 (UL 94), and cone calorimeter testing. For GRPBT containing 20 wt % of CHP, it achieved a V-0 classification with a high LOI (28.5%). Additionally, the peak heat release rate (PHRR) and total smoke production (TSP) were respectively reduced by around 76% and 45% as compared to the results obtained from GRPBT. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=26029660 [article] Studies on mechanical poperties, thermal degradation, and combustion behaviors of poly(1,4 - butylene terephthalate)/glass fiber/cerium hypophosphite composites [texte imprimé] / Wei Yang, Auteur ; Ningning Hong, Auteur ; Lei Song, Auteur . - 2012 . - pp. 8253-8261. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 24 (Juin 2012) . - pp. 8253-8261 Mots-clés : Composite material Glass fiber Combustion Thermal degradation Mechanical properties Résumé : This work aims to develop glass-fiber reinforced poly(1,4-butylene terephthalate) (GRPBT) composites with enhanced mechanical, thermal stability, and flame retardancy properties using a novel compound, cerium hypophosphite (CHP). Mechanical performance studies showed that both the storage modulus and the tensile strength increased first and then decreased with increasing CHP content. For the GRPBT composite with 15 wt % of CHP, the storage modulus value at 30 °C was 3 times that of GRPBT. Thermogravimetric analysis (TGA) illustrated that low loading of CHP could improve the thermal stability of GRPBT composites. The volatilized esters measured by TGA coupled with FTIR (TGA-FTIR) in the decomposition of GRPBT with 20 wt % of CHP are decreased by about 69%. The combustion properties were evaluated by limiting oxygen index (LOI), Underwriters Laboratories 94 (UL 94), and cone calorimeter testing. For GRPBT containing 20 wt % of CHP, it achieved a V-0 classification with a high LOI (28.5%). Additionally, the peak heat release rate (PHRR) and total smoke production (TSP) were respectively reduced by around 76% and 45% as compared to the results obtained from GRPBT. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=26029660

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