Dispersions of various titania nanoparticles in two different ionic liquids / Alexandra Wittmar in Industrial & engineering chemistry research, Vol. 51 N° 25 (Juin 2012)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 51 N° 25 (Juin 2012) . - pp. 8425-8433 Titre : Dispersions of various titania nanoparticles in two different ionic liquids Type de document : texte imprimé Auteurs : Alexandra Wittmar, Auteur ; Mathias Ulbricht, Auteur Année de publication : 2012 Article en page(s) : pp. 8425-8433 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Ionic liquid Nanoparticle Dispersion Résumé : The dispersibility of different lab-made and commercial TiO2 nanoparticles prepared by gas-phase processes in room temperature ionic liquids was for the first time studied by dynamic light scattering and advanced rheology. The characterization of the nanopowders has been done with transmission electron microscopy, X-ray diffraction analysis, nitrogen adsorption, and Brunauer―Emmett―Teller (BET) analysis and FT-IR spectroscopy. The colloidal stabilities of the resulting dispersions were strongly influenced by particle characteristics such as aggregation level, mean particle size, and surface functionality. The period of the ultrasound treatment, the powder concentration in the dispersion, and the hydrophilicity of the ionic liquid were also important influences. It was found that most types of powders disperse better in the hydrophilic ionic liquid because of the hydroxyl groups and adsorbed water present on the powders' surfaces. The best dispersions over a broader concentration range were obtained for a lab-made powder produced by chemical vapor synthesis (aerosol method) which had the smallest nonaggregated particles. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=26066770 [article] Dispersions of various titania nanoparticles in two different ionic liquids [texte imprimé] / Alexandra Wittmar, Auteur ; Mathias Ulbricht, Auteur . - 2012 . - pp. 8425-8433. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 25 (Juin 2012) . - pp. 8425-8433 Mots-clés : Ionic liquid Nanoparticle Dispersion Résumé : The dispersibility of different lab-made and commercial TiO2 nanoparticles prepared by gas-phase processes in room temperature ionic liquids was for the first time studied by dynamic light scattering and advanced rheology. The characterization of the nanopowders has been done with transmission electron microscopy, X-ray diffraction analysis, nitrogen adsorption, and Brunauer―Emmett―Teller (BET) analysis and FT-IR spectroscopy. The colloidal stabilities of the resulting dispersions were strongly influenced by particle characteristics such as aggregation level, mean particle size, and surface functionality. The period of the ultrasound treatment, the powder concentration in the dispersion, and the hydrophilicity of the ionic liquid were also important influences. It was found that most types of powders disperse better in the hydrophilic ionic liquid because of the hydroxyl groups and adsorbed water present on the powders' surfaces. The best dispersions over a broader concentration range were obtained for a lab-made powder produced by chemical vapor synthesis (aerosol method) which had the smallest nonaggregated particles. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=26066770

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