Documents disponibles écrits par cet auteur

Biphasic model describing soybean oil epoxidation with H2O2 in continuous reactors / E. Santacesaria in Industrial & engineering chemistry research, Vol. 51 N° 26 (Juillet 2012) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 51 N° 26 (Juillet 2012) . - pp. 8760–8767 Titre : Biphasic model describing soybean oil epoxidation with H2O2 in continuous reactors Type de document : texte imprimé Auteurs : E. Santacesaria, Auteur ; A. Renken, Auteur ; V. Russo, Auteur Année de publication : 2012 Article en page(s) : pp. 8760–8767 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Biphasic  Continuous  reactors Résumé : Epoxidized soybean oil (ESBO) is produced in industry by reacting soybean oil, at 60–70 °C, with hydrogen peroxide in the presence of formic or acetic acid. A small amount of sulphuric or phosphoric acid is necessary to catalyze the oxidation of the carboxylic acid to the corresponding per-carboxylic acid. Per-carboxylic acid, formed in situ, migrates from the aqueous phase to the oil phase where it spontaneously reacts with the double bonds to give an oxirane ring. This reaction is extremely exothermic (ΔH = −55 kcal/mol) and must be kept under thermal control. Two undesired side reactions can occur: the oxirane ring-opening and the hydrogen peroxide decomposition. In a previous work, a biphasic kinetic model for describing the epoxidation of soybean oil in fed or pulse-fed-batch reactors has been developed and the parameters of the model have been determined by mathematical regression analysis. In the present paper, the model has been adapted to simulate also kinetic runs performed in two continuous tubular reactors of different sizes, filled with spheres of stainless steel (AISI 316) used as static mixer. The agreement found, in simulating the continuous runs, validates the developed biphasic kinetic model. This model constitutes a valid base for the design of a continuous process and for promoting the process intensification. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie2016174 [article] Biphasic model describing soybean oil epoxidation with H2O2 in continuous reactors [texte imprimé] / E. Santacesaria, Auteur ; A. Renken, Auteur ; V. Russo, Auteur . - 2012 . - pp. 8760–8767. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 26 (Juillet 2012) . - pp. 8760–8767 Mots-clés : Biphasic  Continuous  reactors Résumé : Epoxidized soybean oil (ESBO) is produced in industry by reacting soybean oil, at 60–70 °C, with hydrogen peroxide in the presence of formic or acetic acid. A small amount of sulphuric or phosphoric acid is necessary to catalyze the oxidation of the carboxylic acid to the corresponding per-carboxylic acid. Per-carboxylic acid, formed in situ, migrates from the aqueous phase to the oil phase where it spontaneously reacts with the double bonds to give an oxirane ring. This reaction is extremely exothermic (ΔH = −55 kcal/mol) and must be kept under thermal control. Two undesired side reactions can occur: the oxirane ring-opening and the hydrogen peroxide decomposition. In a previous work, a biphasic kinetic model for describing the epoxidation of soybean oil in fed or pulse-fed-batch reactors has been developed and the parameters of the model have been determined by mathematical regression analysis. In the present paper, the model has been adapted to simulate also kinetic runs performed in two continuous tubular reactors of different sizes, filled with spheres of stainless steel (AISI 316) used as static mixer. The agreement found, in simulating the continuous runs, validates the developed biphasic kinetic model. This model constitutes a valid base for the design of a continuous process and for promoting the process intensification. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie2016174