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Modeling of chemical equilibrium and gas phase behavior for the direct synthesis of dimethyl carbonate from CO2 and methanol

Felipe Bustamante, Auteur ; Andrés F. Orrego, Auteur ; Sebastian Villegas, Auteur |

Dans Industrial & engineering chemistry research (Vol. 51 N° 26, Juillet 2012)

The chemical and gas phase equilibrium of the direct synthesis of dimethyl carbonate (DMC) from methanol (MeOH) and CO2 was modeled under mild conditions of temperature and pressure. Deviations from ideality for the quaternary mixture (CO2 + MeO[...]

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