Investigation of Cu - based catalyst for direct synthesis of ethyl acetate from ethanol / Li Xiaofei in Industrial & engineering chemistry research, Vol. 51 N° 26 (Juillet 2012)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 51 N° 26 (Juillet 2012) . - pp. 8974-8978 Titre : Investigation of Cu - based catalyst for direct synthesis of ethyl acetate from ethanol : Improvement of thermal stability of Cu – Cr – Zr composite oxide catalyst by addition of Mn Promoter Type de document : texte imprimé Auteurs : Li Xiaofei, Auteur ; Jiang Haoxi, Auteur ; Li Guiming, Auteur Année de publication : 2012 Article en page(s) : pp. 8974-8978 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Promoter Composite material Thermal stability Catalyst Résumé : A Mn promoter was introduced into a Cu-Cr-Zr composite oxide catalyst for the direct synthesis of ethyl acetate from ethanol dehydrogenation by means of coprecipitation method. The effects of the Mn promoter on the structure and catalytic performance of the catalyst were investigated with characterization techniques including XRD, TPR, XPS, and N2O TPD. An interaction between the Mn promoter and the CuO in the catalyst was found to exist, and it improved the dispersion of the Cu component on the catalyst surface and decreased the size of CuO crystal particles, thereby increasing the thermal stability of the catalyst. The results of long-duration activity tests indicated that the Mn-promoted CCZ (Cu―Cr―Zr) catalyst maintained its activity and showed good stability. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=26107453 [article] Investigation of Cu - based catalyst for direct synthesis of ethyl acetate from ethanol : Improvement of thermal stability of Cu – Cr – Zr composite oxide catalyst by addition of Mn Promoter [texte imprimé] / Li Xiaofei, Auteur ; Jiang Haoxi, Auteur ; Li Guiming, Auteur . - 2012 . - pp. 8974-8978. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 26 (Juillet 2012) . - pp. 8974-8978 Mots-clés : Promoter Composite material Thermal stability Catalyst Résumé : A Mn promoter was introduced into a Cu-Cr-Zr composite oxide catalyst for the direct synthesis of ethyl acetate from ethanol dehydrogenation by means of coprecipitation method. The effects of the Mn promoter on the structure and catalytic performance of the catalyst were investigated with characterization techniques including XRD, TPR, XPS, and N2O TPD. An interaction between the Mn promoter and the CuO in the catalyst was found to exist, and it improved the dispersion of the Cu component on the catalyst surface and decreased the size of CuO crystal particles, thereby increasing the thermal stability of the catalyst. The results of long-duration activity tests indicated that the Mn-promoted CCZ (Cu―Cr―Zr) catalyst maintained its activity and showed good stability. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=26107453

Exemplaires

Code-barres	Cote	Support	Localisation	Section	Disponibilité
aucun exemplaire