Comparative characterization of lignins extracted from cotton stalk based on complete dissolution in different systems / Lingyan Meng in Industrial & engineering chemistry research, Vol. 51 N° 29 (Juillet 2012)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 51 N° 29 (Juillet 2012) . - pp. 9858-9866 Titre : Comparative characterization of lignins extracted from cotton stalk based on complete dissolution in different systems Type de document : texte imprimé Auteurs : Lingyan Meng, Auteur ; Sumin Kang, Auteur ; Xueming Zhang, Auteur Année de publication : 2012 Article en page(s) : pp. 9858-9866 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Dissolution Extract Résumé : A method for the isolation of lignin in high purity from cotton stalk is presented in this study. Lignin fractions were obtained by dissolution of ball-milled cotton stalk in lithium chloride/dimethylacetamide (LiCl/DMAc), tetrabutylammonium fluoride/dimethylsulfoxide (TBAF/DMSO), lithium chloride/N-methyl-2-pyrrolidone (LiCl/NMP), NaOH/urea/H2O, NaOH/thiourea/H2O, and 1-allyl-3-methylimidazolium chloride/dimethylsulfoxide ([Amim]Cl/DMSO) followed by precipitation in the course of which lignin and carbohydrate fractions were separated. Structural elucidation of the lignin fractions was investigated by sugar analysis, FT-IR, and 1D/2D NMR spectroscopy. The results showed that the separated lignin fractions possessed higher purities and molecular weights than MWL. 1D/2D NMR spectra demonstrated that guaiacyl (G) and syringyl (S) units were predominant in the lignin fractions, and a small amount of p-hydroxyphenyl (H) unit was also detected. Moreover, the separated lignin fractions consisted mainly of β-O-4' aryl ether linkages (0.36―0.61/Ar), followed by resinol (0.05—0.08/Ar) and phenylcoumaran structures (0.03—0.05/Ar). In consideration of the relatively high yield and purity and limited structural changes, isolation of lignin from ball-milled materials by complete dissolution in [Amim]Cl/DMSO provided us a more effective approach as compared with the other systems. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=26184964 [article] Comparative characterization of lignins extracted from cotton stalk based on complete dissolution in different systems [texte imprimé] / Lingyan Meng, Auteur ; Sumin Kang, Auteur ; Xueming Zhang, Auteur . - 2012 . - pp. 9858-9866. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 29 (Juillet 2012) . - pp. 9858-9866 Mots-clés : Dissolution Extract Résumé : A method for the isolation of lignin in high purity from cotton stalk is presented in this study. Lignin fractions were obtained by dissolution of ball-milled cotton stalk in lithium chloride/dimethylacetamide (LiCl/DMAc), tetrabutylammonium fluoride/dimethylsulfoxide (TBAF/DMSO), lithium chloride/N-methyl-2-pyrrolidone (LiCl/NMP), NaOH/urea/H2O, NaOH/thiourea/H2O, and 1-allyl-3-methylimidazolium chloride/dimethylsulfoxide ([Amim]Cl/DMSO) followed by precipitation in the course of which lignin and carbohydrate fractions were separated. Structural elucidation of the lignin fractions was investigated by sugar analysis, FT-IR, and 1D/2D NMR spectroscopy. The results showed that the separated lignin fractions possessed higher purities and molecular weights than MWL. 1D/2D NMR spectra demonstrated that guaiacyl (G) and syringyl (S) units were predominant in the lignin fractions, and a small amount of p-hydroxyphenyl (H) unit was also detected. Moreover, the separated lignin fractions consisted mainly of β-O-4' aryl ether linkages (0.36―0.61/Ar), followed by resinol (0.05—0.08/Ar) and phenylcoumaran structures (0.03—0.05/Ar). In consideration of the relatively high yield and purity and limited structural changes, isolation of lignin from ball-milled materials by complete dissolution in [Amim]Cl/DMSO provided us a more effective approach as compared with the other systems. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=26184964

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