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Helium Recovery by a Cu-BTC Metal–Organic-Framework Membrane / Fa Cao in Industrial & engineering chemistry research, Vol. 51 N° 34 (Août 2012) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 51 N° 34 (Août 2012) . - pp. 11274-11278 Titre : Helium Recovery by a Cu-BTC Metal–Organic-Framework Membrane Type de document : texte imprimé Auteurs : Fa Cao, Auteur ; Chunjuan Zhang, Auteur ; Yuanlong Xiao, Auteur Année de publication : 2012 Article en page(s) : pp. 11274-11278 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Gas  separation  membranes Résumé : Highly diverse structures and pore sizes make metal–organic frameworks (MOFs) good candidates for the fabrication of gas separation membranes. The synthesis of continuous MOF membranes still remains a challenge. In this work, an integrated Cu-BTC membrane was successfully prepared on the novel potassium hexatitanate support for the first time by in situ solvothermal growth. This kind of support was found to be more suitable for the growth of Cu2+-containing MOF membranes than other traditional supports, such as a porous alumina support. The permeation results of Cu-BTC membranes obtained in this work show moderate separation selectivities of helium over other small gas molecules, including CO2, N2, and CH4. Compared to other MOF membranes, the Cu-BTC membrane exhibits higher ideal selectivity for helium under the condition of similar helium permeance, while it has higher helium permeance with similar ideal selectivity. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie301445p [article] Helium Recovery by a Cu-BTC Metal–Organic-Framework Membrane [texte imprimé] / Fa Cao, Auteur ; Chunjuan Zhang, Auteur ; Yuanlong Xiao, Auteur . - 2012 . - pp. 11274-11278. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 34 (Août 2012) . - pp. 11274-11278 Mots-clés : Gas  separation  membranes Résumé : Highly diverse structures and pore sizes make metal–organic frameworks (MOFs) good candidates for the fabrication of gas separation membranes. The synthesis of continuous MOF membranes still remains a challenge. In this work, an integrated Cu-BTC membrane was successfully prepared on the novel potassium hexatitanate support for the first time by in situ solvothermal growth. This kind of support was found to be more suitable for the growth of Cu2+-containing MOF membranes than other traditional supports, such as a porous alumina support. The permeation results of Cu-BTC membranes obtained in this work show moderate separation selectivities of helium over other small gas molecules, including CO2, N2, and CH4. Compared to other MOF membranes, the Cu-BTC membrane exhibits higher ideal selectivity for helium under the condition of similar helium permeance, while it has higher helium permeance with similar ideal selectivity. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie301445p