[article]
Titre : |
Citrate route to prepare K-doped Li2ZrO3 sorbents with excellent CO2 capture properties |
Type de document : |
texte imprimé |
Auteurs : |
Qiang Xiao, Auteur ; Xiaodan Tang, Auteur ; Yefeng Liu, Auteur |
Année de publication : |
2012 |
Article en page(s) : |
pp. 231–235 |
Note générale : |
Génie chimique |
Langues : |
Anglais (eng) |
Mots-clés : |
Nanoparticles Citrate CO2 capture K-doped Li2ZrO3 Hydrogen production |
Résumé : |
K-doped Li2ZrO3 sorbents with excellent CO2 capture properties were synthesized via a citrate route. The CO2 capture–regeneration properties of these synthesized K-doped Li2ZrO3 sorbents were investigated by thermogravimetric analysis (TGA) at different temperatures and CO2 partial pressures. The synthesized K-doped Li2ZrO3 sorbents possess a better CO2 capture performance than reported Li2ZrO3-based ones, especially at low CO2 partial pressures. At 823 K and a CO2 partial pressure of 0.25 bar, the uptake of CO2 in the K-doped Li2ZrO3 with an optimized K:Li:Zr composition of 0.2:1.6:1 in molar ratio can reach 23 wt.% within 15 min. Furthermore, the sorbent displays a good stability, confirmed by CO2 capture–regeneration cycles. |
ISSN : |
1385-8947 |
En ligne : |
http://www.sciencedirect.com/science/article/pii/S1385894711010631 |
in Chemical engineering journal > Vol. 174 N° 1 (Octobre 2011) . - pp. 231–235
[article] Citrate route to prepare K-doped Li2ZrO3 sorbents with excellent CO2 capture properties [texte imprimé] / Qiang Xiao, Auteur ; Xiaodan Tang, Auteur ; Yefeng Liu, Auteur . - 2012 . - pp. 231–235. Génie chimique Langues : Anglais ( eng) in Chemical engineering journal > Vol. 174 N° 1 (Octobre 2011) . - pp. 231–235
Mots-clés : |
Nanoparticles Citrate CO2 capture K-doped Li2ZrO3 Hydrogen production |
Résumé : |
K-doped Li2ZrO3 sorbents with excellent CO2 capture properties were synthesized via a citrate route. The CO2 capture–regeneration properties of these synthesized K-doped Li2ZrO3 sorbents were investigated by thermogravimetric analysis (TGA) at different temperatures and CO2 partial pressures. The synthesized K-doped Li2ZrO3 sorbents possess a better CO2 capture performance than reported Li2ZrO3-based ones, especially at low CO2 partial pressures. At 823 K and a CO2 partial pressure of 0.25 bar, the uptake of CO2 in the K-doped Li2ZrO3 with an optimized K:Li:Zr composition of 0.2:1.6:1 in molar ratio can reach 23 wt.% within 15 min. Furthermore, the sorbent displays a good stability, confirmed by CO2 capture–regeneration cycles. |
ISSN : |
1385-8947 |
En ligne : |
http://www.sciencedirect.com/science/article/pii/S1385894711010631 |
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