Synthesis of Co oxide doped carbon aerogel catalyst and catalytic performance in heterogeneous oxidation of phenol in water / Yasnessya Hardjono in Chemical engineering journal, Vol. 174 N° 1 (Octobre 2011)  

Public ISBD [article]  inChemical engineering journal > Vol. 174 N° 1 (Octobre 2011) . - pp.376–382 Titre : Synthesis of Co oxide doped carbon aerogel catalyst and catalytic performance in heterogeneous oxidation of phenol in water Type de document : texte imprimé Auteurs : Yasnessya Hardjono, Auteur ; Hongqi Sun, Auteur ; Huyong Tian, Auteur Année de publication : 2012 Article en page(s) : pp.376–382 Note générale : Génie chimique Langues : Anglais (eng) Mots-clés : Phenol Carbon aerogel Cobalt oxide Heterogeneous oxidation Oxone Résumé : Co oxide doped carbon aerogel (Co/CA) was prepared, characterised by several techniques, and tested for heterogeneous oxidation of phenol in aqueous solution using oxone as an oxidant. For a comparison, homogeneous oxidation of phenol in Co2+/oxone was also investigated. It was found that homogeneous oxidation of phenol using Co2+/oxone was more effective than Co2+/H2O2 and homogeneous oxidation was faster than heterogeneous Co/CA–oxone. Heterogeneous oxidation of phenol in Co/CA–oxone system followed first order kinetics and the activation energy of the heterogeneous system was estimated to be 62.9 kJ/mol. Several factors influencing phenol degradation in the heterogeneous oxidation were studied. Co/CA loading played a more important role in phenol degradation than oxone concentration, and the presence of other organics in solution resulted in a lower phenol oxidation. ISSN : 1385-8947 En ligne : http://www.sciencedirect.com/science/article/pii/S1385894711010679# [article] Synthesis of Co oxide doped carbon aerogel catalyst and catalytic performance in heterogeneous oxidation of phenol in water [texte imprimé] / Yasnessya Hardjono, Auteur ; Hongqi Sun, Auteur ; Huyong Tian, Auteur . - 2012 . - pp.376–382. Génie chimique Langues : Anglais (eng) in Chemical engineering journal > Vol. 174 N° 1 (Octobre 2011) . - pp.376–382 Mots-clés : Phenol Carbon aerogel Cobalt oxide Heterogeneous oxidation Oxone Résumé : Co oxide doped carbon aerogel (Co/CA) was prepared, characterised by several techniques, and tested for heterogeneous oxidation of phenol in aqueous solution using oxone as an oxidant. For a comparison, homogeneous oxidation of phenol in Co2+/oxone was also investigated. It was found that homogeneous oxidation of phenol using Co2+/oxone was more effective than Co2+/H2O2 and homogeneous oxidation was faster than heterogeneous Co/CA–oxone. Heterogeneous oxidation of phenol in Co/CA–oxone system followed first order kinetics and the activation energy of the heterogeneous system was estimated to be 62.9 kJ/mol. Several factors influencing phenol degradation in the heterogeneous oxidation were studied. Co/CA loading played a more important role in phenol degradation than oxone concentration, and the presence of other organics in solution resulted in a lower phenol oxidation. ISSN : 1385-8947 En ligne : http://www.sciencedirect.com/science/article/pii/S1385894711010679#

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