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On the specific surface area of nanoporous materials / E. Detsi in Acta materialia, Vol. 59 N° 20 (Décembre 2011) 

Public ISBD [article]  in Acta materialia > Vol. 59 N° 20 (Décembre 2011) . - pp. 7488–7497 Titre : On the specific surface area of nanoporous materials Type de document : texte imprimé Auteurs : E. Detsi, Auteur ; E. De Jong, Auteur ; A. Zinchenko, Auteur Année de publication : 2012 Article en page(s) : pp. 7488–7497 Note générale : Métallurgie Langues : Anglais (eng) Mots-clés : Specific  surface  area  Nanoporous  materials  Catalysts  Sensors  Actuators Résumé : A proper quantification of the specific surface area of nanoporous materials is necessary for a better understanding of the properties that are affected by the high surface-area-to-volume ratio of nanoporous metals, nanoporous polymers and nanoporous ceramics. In this paper we derive an analytical expression that relates the specific surface area of arbitrary nanoporous materials to their solid bulk density and ligament size. Computed specific surface areas of porous materials with regular nanopores are in good agreement with the expression derived. These regular void geometries include single and double gyroid structures, as well as materials with spherical and cylindrical nanopores. Validation of the expression for disordered nanoporous materials is performed by investigation of the specific surface areas of various nanoporous gold electrodes in the double-layer charging regime. ISSN : 1359-6454 En ligne : http://www.sciencedirect.com/science/article/pii/S1359645411006008 [article] On the specific surface area of nanoporous materials [texte imprimé] / E. Detsi, Auteur ; E. De Jong, Auteur ; A. Zinchenko, Auteur . - 2012 . - pp. 7488–7497. Métallurgie Langues : Anglais (eng) in Acta materialia > Vol. 59 N° 20 (Décembre 2011) . - pp. 7488–7497 Mots-clés : Specific  surface  area  Nanoporous  materials  Catalysts  Sensors  Actuators Résumé : A proper quantification of the specific surface area of nanoporous materials is necessary for a better understanding of the properties that are affected by the high surface-area-to-volume ratio of nanoporous metals, nanoporous polymers and nanoporous ceramics. In this paper we derive an analytical expression that relates the specific surface area of arbitrary nanoporous materials to their solid bulk density and ligament size. Computed specific surface areas of porous materials with regular nanopores are in good agreement with the expression derived. These regular void geometries include single and double gyroid structures, as well as materials with spherical and cylindrical nanopores. Validation of the expression for disordered nanoporous materials is performed by investigation of the specific surface areas of various nanoporous gold electrodes in the double-layer charging regime. ISSN : 1359-6454 En ligne : http://www.sciencedirect.com/science/article/pii/S1359645411006008