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Polymers (Polyvinylpyrrolidones) as active additives modifying the lubricating properties of water / Marian W. Sulek in Industrial & engineering chemistry research, Vol. 51 N° 45 (Novembre 2012) 

Public ISBD [article]  in Industrial & engineering chemistry research > Vol. 51 N° 45 (Novembre 2012) . - pp. 14700-14707 Titre : Polymers (Polyvinylpyrrolidones) as active additives modifying the lubricating properties of water Type de document : texte imprimé Auteurs : Marian W. Sulek, Auteur ; Witold Sas, Auteur ; Tomasz Wasilewski, Auteur Année de publication : 2013 Article en page(s) : pp. 14700-14707 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Additive Résumé : Surface active compounds may act as effective additives modifying water lubricity. Their action mechanism consists in the formation of a lubricating film enriched with an active compound. The reasons for the choice of polyvinylpyrrolidones as additives were their physiological inertness and a lack of harmful environmental effects. The tests were carried out on the solutions of two polyvinylpyrrolidones with degrees of polymerization of 450 (PVP 450) and 14400 (PVP 14400). A significant effect of the polymer chain length on physicochemical (viscosity, surface tension, wettability of steel) and tribological properties (resistance to motion, wear, scuffing) has been found. PVP 14400 showed a considerably greater ability to thicken solutions. Over 10 times higher coefficients of viscosity relative to an analogous PVP 450 solution were observed already at a concentration of 5%. A slightly higher ability of PVP 14400 to reduce surface tension was observed. In the case of wettability of steel, a more effective decrease in the wetting angle was observed for PVP 450. However, the differences obtained were not large and usually did not exceed 20%. The measurements of resistance to motion and wear at three constant loads (2000, 3000, 4000 N) as well as tests on antiseizure abilities under a constant velocity increment of load (409 N/s) were carried out using a four-ball tester (T-02 tester). All friction pairs were made of bearing steel. Introducing additives to water significantly affects a decrease in resistance to motion and wear as well as an increase in the ability of a tribological system to prevent seizure. The system did not undergo seizure even at a load of 4 kN. A 2-fold decrease in the coefficient of friction (μ) and an over 30% decrease in the value of wear scar diameters (d) relative to water were observed for PVP 450 and PVP 14400 solutions at 2.0 kN. The use of water as a lubricant led to seizure of the tribological system already at above 2 kN. Addition of the polymers to water also results in a significant improvement in its antiseizure properties. The values of scuffing load (Pt) and limiting pressure of seizure (poz) for individual solutions were even 5 and 15 times higher, respectively, than the values for water. Seizure load (Poz) was also relatively high, and its level was almost two times higher than that for water. The results obtained indicate that polyvinylpyrrolidone used as an additive considerably improves the tribological characteristics of water as a lubricant base. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=26620383 [article] Polymers (Polyvinylpyrrolidones) as active additives modifying the lubricating properties of water [texte imprimé] / Marian W. Sulek, Auteur ; Witold Sas, Auteur ; Tomasz Wasilewski, Auteur . - 2013 . - pp. 14700-14707. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 45 (Novembre 2012) . - pp. 14700-14707 Mots-clés : Additive Résumé : Surface active compounds may act as effective additives modifying water lubricity. Their action mechanism consists in the formation of a lubricating film enriched with an active compound. The reasons for the choice of polyvinylpyrrolidones as additives were their physiological inertness and a lack of harmful environmental effects. The tests were carried out on the solutions of two polyvinylpyrrolidones with degrees of polymerization of 450 (PVP 450) and 14400 (PVP 14400). A significant effect of the polymer chain length on physicochemical (viscosity, surface tension, wettability of steel) and tribological properties (resistance to motion, wear, scuffing) has been found. PVP 14400 showed a considerably greater ability to thicken solutions. Over 10 times higher coefficients of viscosity relative to an analogous PVP 450 solution were observed already at a concentration of 5%. A slightly higher ability of PVP 14400 to reduce surface tension was observed. In the case of wettability of steel, a more effective decrease in the wetting angle was observed for PVP 450. However, the differences obtained were not large and usually did not exceed 20%. The measurements of resistance to motion and wear at three constant loads (2000, 3000, 4000 N) as well as tests on antiseizure abilities under a constant velocity increment of load (409 N/s) were carried out using a four-ball tester (T-02 tester). All friction pairs were made of bearing steel. Introducing additives to water significantly affects a decrease in resistance to motion and wear as well as an increase in the ability of a tribological system to prevent seizure. The system did not undergo seizure even at a load of 4 kN. A 2-fold decrease in the coefficient of friction (μ) and an over 30% decrease in the value of wear scar diameters (d) relative to water were observed for PVP 450 and PVP 14400 solutions at 2.0 kN. The use of water as a lubricant led to seizure of the tribological system already at above 2 kN. Addition of the polymers to water also results in a significant improvement in its antiseizure properties. The values of scuffing load (Pt) and limiting pressure of seizure (poz) for individual solutions were even 5 and 15 times higher, respectively, than the values for water. Seizure load (Poz) was also relatively high, and its level was almost two times higher than that for water. The results obtained indicate that polyvinylpyrrolidone used as an additive considerably improves the tribological characteristics of water as a lubricant base. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=26620383