Fundamentals of petroleum residue cracking gasification for coproduction of oil and syngas / YuMing Zhang in Industrial & engineering chemistry research, Vol. 51 N° 46 (Novembre 2012)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 51 N° 46 (Novembre 2012) . - pp. 15032-15040 Titre : Fundamentals of petroleum residue cracking gasification for coproduction of oil and syngas Type de document : texte imprimé Auteurs : YuMing Zhang, Auteur ; Deping Yu, Auteur ; Wangliang Li, Auteur Année de publication : 2013 Article en page(s) : pp. 15032-15040 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Synthesis gas Gasification Cracking Petroleum Résumé : Vacuum residue (VR) was stepwise converted via catalytic cracking for liquid and coke gasification for hydrogen-rich syngas in a fluidized bed reactor. Silica sand and spent equilibrium FCC (E-FCC) catalyst were used as the catalysts for VR cracking. The liquid yield was about 89 wt % at 568 °C using silica sand as catalyst and the conversion ratio of heavy fractions was only 55%. About 60 wt % VR was converted into gas and coke over the E-FCC catalyst at 480 °C, showing that the catalyst had too strong acidity for VR cracking. The E-FCC catalyst was thus modified (aged) with both hydrothermal treatment and impregnation of alkali and alkaline-earth metals (K and Mg) to weaken its acidity and facilitate the liquid oil production. The aged FCC (A-FCC) catalyst exhibited appropriate cracking activity to allow both the expected liquid yield of about 80 wt % and heavy fraction conversion ratio of up to 98 wt %. Steam gasification of the deposited coke on the surface of the A-FCC catalyst resulted in the production of syngas containing CO and H2 content to be about 45 and 42 vol %, respectively. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=26679622 [article] Fundamentals of petroleum residue cracking gasification for coproduction of oil and syngas [texte imprimé] / YuMing Zhang, Auteur ; Deping Yu, Auteur ; Wangliang Li, Auteur . - 2013 . - pp. 15032-15040. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 46 (Novembre 2012) . - pp. 15032-15040 Mots-clés : Synthesis gas Gasification Cracking Petroleum Résumé : Vacuum residue (VR) was stepwise converted via catalytic cracking for liquid and coke gasification for hydrogen-rich syngas in a fluidized bed reactor. Silica sand and spent equilibrium FCC (E-FCC) catalyst were used as the catalysts for VR cracking. The liquid yield was about 89 wt % at 568 °C using silica sand as catalyst and the conversion ratio of heavy fractions was only 55%. About 60 wt % VR was converted into gas and coke over the E-FCC catalyst at 480 °C, showing that the catalyst had too strong acidity for VR cracking. The E-FCC catalyst was thus modified (aged) with both hydrothermal treatment and impregnation of alkali and alkaline-earth metals (K and Mg) to weaken its acidity and facilitate the liquid oil production. The aged FCC (A-FCC) catalyst exhibited appropriate cracking activity to allow both the expected liquid yield of about 80 wt % and heavy fraction conversion ratio of up to 98 wt %. Steam gasification of the deposited coke on the surface of the A-FCC catalyst resulted in the production of syngas containing CO and H2 content to be about 45 and 42 vol %, respectively. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=26679622

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