Solid-state polymerization of semiaromatic copolyamides of nylon-4,T and Nylon-4,6 / Young Jun Kim in Industrial & engineering chemistry research, Vol. 51 N° 49 (Décembre 2012)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 51 N° 49 (Décembre 2012) . - pp. 15801–15810 Titre : Solid-state polymerization of semiaromatic copolyamides of nylon-4,T and Nylon-4,6 : Composition ratio effect and thermal properties Type de document : texte imprimé Auteurs : Young Jun Kim, Auteur ; Kurnia Endah Yohana, Auteur ; Hong-shik Lee, Auteur Année de publication : 2013 Article en page(s) : pp. 15801–15810 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Thermal properties Polymerization Résumé : Solid-state polymerization (SSP) of semiaromatic copolyamides composed of nylon-4,T and nylon-4,6 in different molar ratios were investigated using a mixture of nitrogen and steam as the sweep fluid at reaction temperatures in the range of 220–260 °C. Prepolymers having different nylon-4,T contents (28.2, 37.9, and 47.8 mol %) were synthesized by melt polyamidation with stoichiometric ratios of diamine and diacid. The SSP conditions were carefully chosen to eliminate the influences of both internal and external diffusion of the reaction byproducts. Under these conditions, a high-molecular-weight semiaromatic copolyamide with an intrinsic viscosity of 2.469 dL/g was obtained upon SSP at 260 °C for 48 h. As the nylon-4,T content increased, the SSP rate decreased owing to the inherently low reactivity of the aromatic diacid and inhibition of chain-end mobility. The glass transition, melting, and decomposition temperatures of the polymers synthesized from the higher-nylon-4,T-content prepolymer were always higher than those of the polymers synthesized from the lower-nylon-4,T-content prepolymer. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=26732105 [article] Solid-state polymerization of semiaromatic copolyamides of nylon-4,T and Nylon-4,6 : Composition ratio effect and thermal properties [texte imprimé] / Young Jun Kim, Auteur ; Kurnia Endah Yohana, Auteur ; Hong-shik Lee, Auteur . - 2013 . - pp. 15801–15810. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 49 (Décembre 2012) . - pp. 15801–15810 Mots-clés : Thermal properties Polymerization Résumé : Solid-state polymerization (SSP) of semiaromatic copolyamides composed of nylon-4,T and nylon-4,6 in different molar ratios were investigated using a mixture of nitrogen and steam as the sweep fluid at reaction temperatures in the range of 220–260 °C. Prepolymers having different nylon-4,T contents (28.2, 37.9, and 47.8 mol %) were synthesized by melt polyamidation with stoichiometric ratios of diamine and diacid. The SSP conditions were carefully chosen to eliminate the influences of both internal and external diffusion of the reaction byproducts. Under these conditions, a high-molecular-weight semiaromatic copolyamide with an intrinsic viscosity of 2.469 dL/g was obtained upon SSP at 260 °C for 48 h. As the nylon-4,T content increased, the SSP rate decreased owing to the inherently low reactivity of the aromatic diacid and inhibition of chain-end mobility. The glass transition, melting, and decomposition temperatures of the polymers synthesized from the higher-nylon-4,T-content prepolymer were always higher than those of the polymers synthesized from the lower-nylon-4,T-content prepolymer. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=26732105

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