Esterification of Acrylic Acid and n-Butanol in a Pilot-Scale Reactive Distillation Column—Experimental Investigation, Model Validation, and Process Analysis / Alexander Niesbach in Industrial & engineering chemistry research, Vol. 51 N° 50 (Décembre 2012)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 51 N° 50 (Décembre 2012) . - pp. 16444-16456 Titre : Esterification of Acrylic Acid and n-Butanol in a Pilot-Scale Reactive Distillation Column—Experimental Investigation, Model Validation, and Process Analysis Type de document : texte imprimé Auteurs : Alexander Niesbach, Auteur ; Ron Fuhrmeister, Auteur ; Tobias Keller, Auteur Année de publication : 2013 Article en page(s) : pp. 16444-16456 Note générale : Industrial chemistry Langues : Anglais (eng) Mots-clés : Modeling Distillation column with reactionEsterification Résumé : Due to a high risk of polymerization and complex thermodynamic behavior of the chemical system, the current production process for n-butyl acrylate synthesis is cost-intensive and challenging. Reactive distillation integrates chemical reactions and distillation into one unit at the same time and is one of the best-known examples of process intensification. To facilitate industrial application of this concept for the production of n-butyl acrylate, reliable experimental data are required. This article presents an experimental and theoretical investigation of the synthesis of n-butyl acrylate using reactive distillation. Experiments were conducted in a pilot-scale reactive distillation column, and the decisive operational parameters were varied. To predict the experimental results, a nonequilibrium-stage model was applied and the model was validated using the experimental data. The validated model was then used to perform a process analysis, showing trends in the conversion of acrylic acid and n-butanol and the purity of n-butyl acrylate that can be used for prospective optimization studies. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=26732173 [article] Esterification of Acrylic Acid and n-Butanol in a Pilot-Scale Reactive Distillation Column—Experimental Investigation, Model Validation, and Process Analysis [texte imprimé] / Alexander Niesbach, Auteur ; Ron Fuhrmeister, Auteur ; Tobias Keller, Auteur . - 2013 . - pp. 16444-16456. Industrial chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 51 N° 50 (Décembre 2012) . - pp. 16444-16456 Mots-clés : Modeling Distillation column with reactionEsterification Résumé : Due to a high risk of polymerization and complex thermodynamic behavior of the chemical system, the current production process for n-butyl acrylate synthesis is cost-intensive and challenging. Reactive distillation integrates chemical reactions and distillation into one unit at the same time and is one of the best-known examples of process intensification. To facilitate industrial application of this concept for the production of n-butyl acrylate, reliable experimental data are required. This article presents an experimental and theoretical investigation of the synthesis of n-butyl acrylate using reactive distillation. Experiments were conducted in a pilot-scale reactive distillation column, and the decisive operational parameters were varied. To predict the experimental results, a nonequilibrium-stage model was applied and the model was validated using the experimental data. The validated model was then used to perform a process analysis, showing trends in the conversion of acrylic acid and n-butanol and the purity of n-butyl acrylate that can be used for prospective optimization studies. ISSN : 0888-5885 En ligne : http://cat.inist.fr/?aModele=afficheN&cpsidt=26732173

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