[article] inIndustrial & engineering chemistry research > Vol. 49 N° 11 (Juin 2010) . - pp. 5400–5406
Titre : |
Rheological behavior of pyrophyllite − water slurry in the presence of anionic, cationic, and nonionic surfactants |
Type de document : |
texte imprimé |
Auteurs : |
Himanshu Desai, Auteur ; Nihar Ranjan Biswal, Auteur ; Santanu Paria, Auteur |
Année de publication : |
2010 |
Article en page(s) : |
pp. 5400–5406 |
Note générale : |
Industrial chemistry |
Langues : |
Anglais (eng) |
Mots-clés : |
surfactants Anionic Cationic |
Résumé : |
The rheological behavior of pyrophyllite−water clay slurry has been studied in the presence of three different types of surfactants: anionic, cationic, and nonionic. The slurry is non-Newtonian and thixotropic in nature, and the hysteresis area increases with increasing clay concentration. In the presence of acidic pH, surface potential is low and viscosity is high; the opposite is true for alkaline pH. The rheological behavior is different in the presence of three surfactants. The viscosity highly depends on the types of surfactant adsorbed on the clay surface and surface potential after the adsorption. The d(001) lattice spacing of the pyrophyllite clay does not change after the adsorption of surfactants, indicating that the surfactants are not adsorbing inside the clay spacing. |
ISSN : |
0888-5885 |
En ligne : |
http://pubs.acs.org/doi/abs/10.1021/ie901643s |
[article] Rheological behavior of pyrophyllite − water slurry in the presence of anionic, cationic, and nonionic surfactants [texte imprimé] / Himanshu Desai, Auteur ; Nihar Ranjan Biswal, Auteur ; Santanu Paria, Auteur . - 2010 . - pp. 5400–5406. Industrial chemistry Langues : Anglais ( eng) in Industrial & engineering chemistry research > Vol. 49 N° 11 (Juin 2010) . - pp. 5400–5406
Mots-clés : |
surfactants Anionic Cationic |
Résumé : |
The rheological behavior of pyrophyllite−water clay slurry has been studied in the presence of three different types of surfactants: anionic, cationic, and nonionic. The slurry is non-Newtonian and thixotropic in nature, and the hysteresis area increases with increasing clay concentration. In the presence of acidic pH, surface potential is low and viscosity is high; the opposite is true for alkaline pH. The rheological behavior is different in the presence of three surfactants. The viscosity highly depends on the types of surfactant adsorbed on the clay surface and surface potential after the adsorption. The d(001) lattice spacing of the pyrophyllite clay does not change after the adsorption of surfactants, indicating that the surfactants are not adsorbing inside the clay spacing. |
ISSN : |
0888-5885 |
En ligne : |
http://pubs.acs.org/doi/abs/10.1021/ie901643s |
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