Self-cleaning films with high transparency based on tiO2 nanoparticles synthesized via flame combustion / Huiting Wang in Industrial & engineering chemistry research, Vol. 49 N° 8 (Avril 2010)  

Public ISBD [article]  inIndustrial & engineering chemistry research > Vol. 49 N° 8 (Avril 2010) . - pp. 3654–3662 Titre : Self-cleaning films with high transparency based on tiO2 nanoparticles synthesized via flame combustion Type de document : texte imprimé Auteurs : Huiting Wang, Auteur ; Yanjie Hu, Auteur ; Ling Zhang, Auteur Année de publication : 2010 Article en page(s) : pp. 3654–3662 Note générale : Industrial Chemistry Langues : Anglais (eng) Mots-clés : Self-Cleaning Films with High Transparency Nanoparticles Synthesized Flame Combustion Résumé : Self-cleaning transparent nanoporous films with high photocatalytic properties were obtained based on the self-assembly of TiO2 nanoparticles synthesized by H2/O2 combustion flames. Films were prepared from multilayer deposition of poly(sodium 4-styrenesulfonate)-treated TiO2 nanoparticles and SiO2 nanoparticles with electrostatic interaction by the adsorption of positively charged poly(diallyldimethylammonium chloride) via layer-by-layer assembly processes. The assembly conditions, such as the pH and concentration of a nanoparticle suspension that cause variation of the surface charge densities, were found to strongly affect the thickness and morphology of multilayer films. TiO2/SiO2 coatings assembled with 10 cycles reach effective photocatalysis with a maximum transmittance of 99.3% as well as a water droplet spreading time as short as 0.29 s. The photodegradation kinetics showed that multilayer films fabricated with 10 cycles are 4 times more active than films assembled with 5 cycles, indicating that flame-synthesized TiO2 with well crystallinity can be used to fabricate high transparent self-cleaning films at suitable assembly conditions. The photocatalytic degradation kinetics dominated by control of the number of assembled cycles was also discussed. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie901782w [article] Self-cleaning films with high transparency based on tiO2 nanoparticles synthesized via flame combustion [texte imprimé] / Huiting Wang, Auteur ; Yanjie Hu, Auteur ; Ling Zhang, Auteur . - 2010 . - pp. 3654–3662. Industrial Chemistry Langues : Anglais (eng) in Industrial & engineering chemistry research > Vol. 49 N° 8 (Avril 2010) . - pp. 3654–3662 Mots-clés : Self-Cleaning Films with High Transparency Nanoparticles Synthesized Flame Combustion Résumé : Self-cleaning transparent nanoporous films with high photocatalytic properties were obtained based on the self-assembly of TiO2 nanoparticles synthesized by H2/O2 combustion flames. Films were prepared from multilayer deposition of poly(sodium 4-styrenesulfonate)-treated TiO2 nanoparticles and SiO2 nanoparticles with electrostatic interaction by the adsorption of positively charged poly(diallyldimethylammonium chloride) via layer-by-layer assembly processes. The assembly conditions, such as the pH and concentration of a nanoparticle suspension that cause variation of the surface charge densities, were found to strongly affect the thickness and morphology of multilayer films. TiO2/SiO2 coatings assembled with 10 cycles reach effective photocatalysis with a maximum transmittance of 99.3% as well as a water droplet spreading time as short as 0.29 s. The photodegradation kinetics showed that multilayer films fabricated with 10 cycles are 4 times more active than films assembled with 5 cycles, indicating that flame-synthesized TiO2 with well crystallinity can be used to fabricate high transparent self-cleaning films at suitable assembly conditions. The photocatalytic degradation kinetics dominated by control of the number of assembled cycles was also discussed. ISSN : 0888-5885 En ligne : http://pubs.acs.org/doi/abs/10.1021/ie901782w

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